{"id":"W1974025055","doi":"10.1039/b711765e","title":"Minimal structural reorganisation in the electrochemical oxidation of a dinuclear, double helical Cu(i) complex of a triazine-based pentadentate ligand","year":2007,"lang":"en","type":"article","venue":"Chemical Communications","topic":"Metal complexes synthesis and properties","field":"Medicine","cited_by":22,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"","keywords":"Electrochemistry; Ligand (biochemistry); Triazine; Chemistry; Double stranded; Crystallography; Stereochemistry; Polymer chemistry; Combinatorial chemistry; Electrode; DNA; Receptor; Biochemistry; Physical chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0005720373,0.0001134357,0.0003118744,0.00009051798,0.00005735831,0.00001133351,0.0004926728,0.00008024347,0.00005380307],"category_scores_gemma":[0.0002234685,0.00008089149,0.0001125761,0.0003494011,0.0003418681,0.00005020615,0.00009643555,0.0002682714,0.000003935119],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00005456511,"about_ca_system_score_gemma":0.00005559701,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00006906917,"about_ca_topic_score_gemma":0.00002529529,"domain_scores_codex":[0.9986877,0.00009311173,0.0006237668,0.0001384464,0.000285878,0.0001710463],"domain_scores_gemma":[0.99835,0.0005048593,0.0001868667,0.000775029,0.0001306269,0.00005267334],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.001046289,0.0002135585,0.002306965,0.00005743174,0.00001800336,3.428183e-7,0.0004791403,1.18889e-7,0.9940967,0.001475622,0.00004094525,0.0002648667],"study_design_scores_gemma":[0.001643762,0.0001176244,0.02456473,0.00005839776,0.00006736535,0.00001701978,0.0002948466,0.0005831859,0.9719923,0.0002840469,0.0002984958,0.0000782026],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.995612,0.0002375166,0.0001973077,0.002172833,0.000007905371,0.0003684107,0.000004416059,0.00001539672,0.001384265],"genre_scores_gemma":[0.9915935,0.00002253623,0.007940224,0.0001893493,0.00002516563,0.00001447291,0.0001914875,0.00001245723,0.00001079308],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02225776,"threshold_uncertainty_score":0.3298659,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.1118646524697804,"score_gpt":0.3494989289434033,"score_spread":0.2376342764736229,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}