{"id":"W1974171827","doi":"10.1002/chin.200046121","title":"ChemInform Abstract: Transannular Diels—Alder Studies of 14‐Membered cis—trans—trans Macrocyclic Trienes Having Allylic Ether or Enone Dienophile.","year":2000,"lang":"en","type":"article","venue":"ChemInform","topic":"Asymmetric Synthesis and Catalysis","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Sherbrooke","funders":"","keywords":"Chemistry; Allylic rearrangement; Enone; Ether; Cis–trans isomerism; Organic chemistry; Stereochemistry; Medicinal chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0003770906,0.0007312918,0.001260885,0.0001866461,0.0002364899,0.00006012623,0.0008087185,0.000526882,0.02321155],"category_scores_gemma":[0.0001666378,0.0005914505,0.0006909775,0.0007546058,0.0004031535,0.0005034124,0.00004892442,0.0004242857,0.0000717229],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001673509,"about_ca_system_score_gemma":0.000105559,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00007056898,"about_ca_topic_score_gemma":0.00004184686,"domain_scores_codex":[0.9961573,3.806513e-7,0.001473237,0.0006225943,0.0008307982,0.0009156426],"domain_scores_gemma":[0.9976762,0.0004691588,0.000385507,0.0009724638,0.0002149222,0.000281742],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"design_other","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0004424883,0.0002751678,0.000038604,0.001139187,0.0009018038,0.00002812955,0.008135237,0.000003796153,0.02420189,0.00001075253,0.001750166,0.9630728],"study_design_scores_gemma":[0.001555315,0.00004920101,0.0001594402,0.0003267967,0.0004758681,0.00003300148,0.003813324,0.00001065658,0.8877981,0.00005454809,0.1049693,0.0007544484],"study_design_candidate":"design_other","study_design_consensus":null,"genre_codex":"other","genre_gemma":"empirical","genre_scores_codex":[0.1165589,0.004271753,0.000003119125,0.0002148082,0.00007364731,0.000245718,0.0001839789,0.000209716,0.8782383],"genre_scores_gemma":[0.9069551,0.003421357,0.00008515084,0.0001058376,0.0002156828,0.0001256656,0.0001242821,0.0001004322,0.08886646],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.9623183,"threshold_uncertainty_score":0.9996537,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02920160962596026,"score_gpt":0.2693468930914679,"score_spread":0.2401452834655077,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}