{"id":"W1974239250","doi":"10.1021/ja067724g","title":"Bioinspired Chemical Inversion of <scp>l</scp>-Amino Acids to <scp>d</scp>-Amino Acids","year":2007,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Chemical Synthesis and Analysis","field":"Biochemistry, Genetics and Molecular Biology","cited_by":90,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Chemistry; Amino acid; Hydrogen bond; Stereochemistry; Biochemistry; Molecule; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002556608,0.0005019024,0.0002972897,0.0001906613,0.0002028784,0.0002625273,0.000561861,0.0004902348,0.00224545],"category_scores_gemma":[0.0002897301,0.0002267208,0.0002457441,0.0001776757,0.0003582187,0.000278414,0.0004618395,0.0006835007,0.0009794066],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004046724,"about_ca_system_score_gemma":0.000272613,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005406726,"about_ca_topic_score_gemma":0.0009112331,"domain_scores_codex":[0.999818,0.00002714972,0.000009984738,0.00004915354,0.00004147283,0.00005424062],"domain_scores_gemma":[0.9998372,0.00003236502,0.00005573301,0.00002203757,0.00002792321,0.00002479634],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000576077,0.0000365683,0.00005430784,0.0002171974,0.000008739092,0.0001018039,0.00003316013,0.0002870434,0.9933815,0.001332386,0.0003474076,0.004142339],"study_design_scores_gemma":[0.00001662055,0.0001007793,0.00009130811,0.000004848724,0.000004358455,0.00009086197,0.000007485733,0.0006384013,0.9953859,0.0000445125,0.00360894,0.000005942062],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9508703,0.003334682,0.0249806,0.0005190864,0.0002982145,0.0001877664,0.000344779,0.000521764,0.01894286],"genre_scores_gemma":[0.9722529,0.001931941,0.01717035,0.0003407726,0.00006742219,0.0001017556,0.0002235809,0.00009342629,0.007817808],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00224545,"threshold_uncertainty_score":0.007511795,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008230121749074136,"score_gpt":0.2404881180652828,"score_spread":0.2322579963162087,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}