{"id":"W1974326170","doi":"10.1016/j.poly.2008.07.033","title":"Synthesis, structural characterization, and DFT investigation of azoimine–ruthenium complexes containing aromatic-nitrogen ligands","year":2008,"lang":"en","type":"article","venue":"Polyhedron","topic":"Metal complexes synthesis and properties","field":"Medicine","cited_by":29,"is_retracted":false,"has_abstract":false,"ca_institutions":"Carleton University","funders":"","keywords":"Diimine; Chemistry; Ruthenium; Acetonitrile; Cyclic voltammetry; Bipyridine; Electrochemistry; Phenanthroline; Density functional theory; Ligand (biochemistry); Absorption spectroscopy; 2,2'-Bipyridine; Crystallography; Medicinal chemistry; Inorganic chemistry; Physical chemistry; Crystal structure; Organic chemistry; Electrode; Catalysis; Computational chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001074636,0.0001012538,0.0002148068,0.0001383067,0.000243521,0.0002453505,0.0003865969,0.0002168331,0.001722597],"category_scores_gemma":[0.0002166649,0.0001063523,0.0000809478,0.0001373903,0.0001324591,0.0001308652,0.0001197332,0.0001791231,0.0001917316],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000259113,"about_ca_system_score_gemma":0.0001292279,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001244153,"about_ca_topic_score_gemma":0.001384018,"domain_scores_codex":[0.9999223,0.00001587357,0.00000474602,0.00001472617,0.00002961554,0.00001280264],"domain_scores_gemma":[0.9999335,0.0000189622,0.00001513787,0.00001033685,0.00001455252,0.000007503112],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0006666585,0.00005590248,0.000696998,0.0001824465,0.00001420887,0.0001626997,0.0001124496,0.001800849,0.9880376,0.002269307,0.0003501203,0.005650785],"study_design_scores_gemma":[0.000053869,0.0005776926,0.002267551,0.000009727619,0.00001985377,0.0002467845,0.00006481738,0.01719462,0.9753693,0.000162389,0.004019302,0.00001408292],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.994282,0.0005088492,0.001724716,0.00007088634,0.000005813147,0.00001306617,0.0001311327,0.00002794814,0.003235525],"genre_scores_gemma":[0.9970926,0.0001241769,0.001630644,0.00001186914,0.000001779241,0.000007867476,0.0001524496,0.00000883886,0.0009698516],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001722597,"threshold_uncertainty_score":0.005762696,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0485179926489397,"score_gpt":0.2481872893474548,"score_spread":0.1996692966985151,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}