{"id":"W1974337796","doi":"10.1021/om0101801","title":"A Stable Silylene in a Reactive Environment:  Synthesis, Reactivity, and Silicon Extrusion Chemistry of a Coordinatively Unsaturated Ruthenium Silylene Complex Containing Chloride and η<sup>3</sup>-P−C−P Ligands","year":2002,"lang":"en","type":"article","venue":"Organometallics","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":69,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"","keywords":"Silylene; Chemistry; Ruthenium; Hydride; Dimer; Reactivity (psychology); Adduct; Siloxane; Ligand (biochemistry); Medicinal chemistry; Agostic interaction; Nuclear magnetic resonance spectroscopy; Ethylene; Carbene; Chloride; Crystallography; Carbyne; Metal; Photochemistry; Stereochemistry; Silicon; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001682854,0.0003818525,0.0002285121,0.0001114323,0.0001267287,0.0003393959,0.0003490821,0.0003406224,0.001016408],"category_scores_gemma":[0.0001313442,0.0001956434,0.0001578833,0.0001283461,0.0002515923,0.0003025029,0.0002072648,0.0002724552,0.0003487447],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003952688,"about_ca_system_score_gemma":0.0001606982,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004004939,"about_ca_topic_score_gemma":0.0007148038,"domain_scores_codex":[0.9998522,0.00002010379,0.000007172338,0.00002915485,0.0000502948,0.00004112457],"domain_scores_gemma":[0.9999204,0.00001060803,0.00002608199,0.000009843657,0.00001087743,0.00002227365],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004556982,0.00001143669,0.00007027981,0.00002226106,0.000004267439,0.00004985957,0.00002291224,0.0001521411,0.9989578,0.000111623,0.00002417687,0.0005276179],"study_design_scores_gemma":[0.000008085092,0.0001392474,0.0003291841,9.980371e-7,0.000004936137,0.00005622537,0.000007507927,0.0005806485,0.9982439,0.000009605487,0.0006168454,0.000002845576],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9957813,0.0002299805,0.002396622,0.00004063716,0.000006227503,0.00001762332,0.00006967163,0.0001016317,0.001356442],"genre_scores_gemma":[0.9971642,0.0001450749,0.001409178,0.00001462087,0.000003503519,0.000007270109,0.0001000884,0.00002963584,0.001126465],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001016408,"threshold_uncertainty_score":0.003400207,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02127558089338296,"score_gpt":0.2046208662318225,"score_spread":0.1833452853384396,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}