{"id":"W1974337796","doi":"10.1021/om0101801","title":"A Stable Silylene in a Reactive Environment:  Synthesis, Reactivity, and Silicon Extrusion Chemistry of a Coordinatively Unsaturated Ruthenium Silylene Complex Containing Chloride and η<sup>3</sup>-P−C−P Ligands","year":2002,"lang":"en","type":"article","venue":"Organometallics","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":69,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"","keywords":"Silylene; Chemistry; Ruthenium; Hydride; Dimer; Reactivity (psychology); Adduct; Siloxane; Ligand (biochemistry); Medicinal chemistry; Agostic interaction; Nuclear magnetic resonance spectroscopy; Ethylene; Carbene; Chloride; Crystallography; Carbyne; Metal; Photochemistry; Stereochemistry; Silicon; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0004346383,0.0006178593,0.00128773,0.0002342598,0.0001881163,0.0001054635,0.0003563759,0.0003154509,0.0113226],"category_scores_gemma":[0.0004438295,0.0006266548,0.0001515068,0.0006161868,0.0004226202,0.0003972568,0.0004446392,0.0004207453,0.0000130368],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002398256,"about_ca_system_score_gemma":0.00004567143,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002288268,"about_ca_topic_score_gemma":0.00001393455,"domain_scores_codex":[0.9970447,0.00006122189,0.0008169287,0.0009948455,0.0004698037,0.0006124791],"domain_scores_gemma":[0.9976219,0.0007980138,0.0005313794,0.0007086538,0.00007639088,0.0002636839],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002129902,0.0005901198,0.00346482,0.0003234177,0.0002725935,0.0000243541,0.001556355,0.00002582544,0.9780399,0.00007495058,0.000005704001,0.01540892],"study_design_scores_gemma":[0.001614011,0.00007436994,0.008226082,0.0002230574,0.0002983629,0.00006876064,0.003058602,0.006601456,0.9748312,0.0001355469,0.00402376,0.0008447785],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9909987,0.001455625,0.00002442735,0.0002083647,0.000009046115,0.0001853516,0.000192537,0.00006982729,0.006856065],"genre_scores_gemma":[0.9965485,0.001598763,0.0001738829,0.00002162998,0.0000658667,0.00005613967,0.00006638698,0.00009644717,0.001372352],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01456415,"threshold_uncertainty_score":0.9996185,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02127558089338296,"score_gpt":0.2046208662318225,"score_spread":0.1833452853384396,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}