{"id":"W1974440523","doi":"10.1039/c4sc00312h","title":"Mapping electrogenerated chemiluminescence reactivity in space: mechanistic insight into model systems used in immunoassays","year":2014,"lang":"en","type":"article","venue":"Chemical Science","topic":"Advanced biosensing and bioanalysis techniques","field":"Biochemistry, Genetics and Molecular Biology","cited_by":261,"is_retracted":false,"has_abstract":true,"ca_institutions":"Canadian Nautical Research Society","funders":"","keywords":"Chemiluminescence; Reactivity (psychology); Space (punctuation); Chemistry; Combinatorial chemistry; Nanotechnology; Computer science; Materials science; Chromatography; Medicine","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0007210576,0.0005909495,0.0002872611,0.0002602671,0.0003000466,0.0008619,0.0007582024,0.001023481,0.0008272637],"category_scores_gemma":[0.0008174836,0.0002311562,0.0003293065,0.0002357082,0.0008738842,0.001319395,0.0003196833,0.001116695,0.0002716698],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004820466,"about_ca_system_score_gemma":0.0003129755,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002552248,"about_ca_topic_score_gemma":0.000173452,"domain_scores_codex":[0.9997453,0.00009076708,0.00001042169,0.00005294205,0.00006156943,0.00003897474],"domain_scores_gemma":[0.9997202,0.0001297881,0.00005813346,0.00003126992,0.0000345728,0.00002607383],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001208833,0.00007089911,0.0002881014,0.00009282,0.000005700058,0.00008480238,0.00007456655,0.001025003,0.9907958,0.004755958,0.00008352459,0.002602054],"study_design_scores_gemma":[0.00001769136,0.0003191887,0.0004806574,0.000007727921,0.000009255269,0.000146224,0.00007483592,0.008791471,0.9851682,0.002072135,0.002900242,0.00001226109],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.7852268,0.003865902,0.2058917,0.0009622372,0.0001284206,0.0001131109,0.0001755288,0.0004088856,0.003227322],"genre_scores_gemma":[0.9614283,0.001909251,0.03476126,0.0001852922,0.00002471239,0.00006822515,0.0001589274,0.00003734097,0.001426629],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001023481,"threshold_uncertainty_score":0.003813326,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009600360342039007,"score_gpt":0.25197396576999,"score_spread":0.242373605427951,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}