{"id":"W1974442869","doi":"10.1021/ol0609863","title":"From Macrocycle Dipeptide Lactams To Azabicyclo[X.Y.0]alkanone Amino Acids:  A Transannular Cyclization Route for Peptide Mimic Synthesis","year":2006,"lang":"en","type":"article","venue":"Organic Letters","topic":"Chemical Synthesis and Analysis","field":"Biochemistry, Genetics and Molecular Biology","cited_by":37,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"Fonds Québécois de la Recherche sur la Nature et les Technologies","keywords":"Dipeptide; Chemistry; Bicyclic molecule; Stereochemistry; Ring (chemistry); Peptide; Beta-lactam; Amino acid; Electrophile; Combinatorial chemistry; Catalysis; Organic chemistry; Biochemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00007978964,0.0003195449,0.0001682721,0.0002043738,0.0001341263,0.0002767683,0.0001908587,0.0002058743,0.002384755],"category_scores_gemma":[0.0001024821,0.0001722185,0.0001330324,0.0001444911,0.0001542271,0.0002121959,0.0002729742,0.0003449318,0.001453488],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001992958,"about_ca_system_score_gemma":0.0002357179,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002137901,"about_ca_topic_score_gemma":0.000418419,"domain_scores_codex":[0.9999505,0.000008080682,0.000003981625,0.00001207293,0.00001302837,0.0000124127],"domain_scores_gemma":[0.9999577,0.000004877967,0.000009331207,0.000003601473,0.000005561407,0.00001892833],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001247906,0.00002489455,0.0001159811,0.00009855728,0.000006409584,0.0002956173,0.00004320518,0.0004215685,0.9856735,0.001627618,0.0001770036,0.01139078],"study_design_scores_gemma":[0.0000412581,0.0007646988,0.0005929786,0.00001761773,0.00001460774,0.0008169609,0.00002001049,0.0008406447,0.9766542,0.0005635743,0.01965937,0.00001410671],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9151306,0.01180368,0.03982482,0.000402963,0.0002618593,0.0003637882,0.000513515,0.0006085177,0.03109023],"genre_scores_gemma":[0.9456029,0.006211346,0.03384618,0.0002233296,0.00005040161,0.0001584256,0.0005107194,0.00008162877,0.01331501],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002384755,"threshold_uncertainty_score":0.007977784,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.003915116014631232,"score_gpt":0.1991515187549497,"score_spread":0.1952364027403185,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}