{"id":"W1974525329","doi":"10.1139/v10-161","title":"Comparison of photoenolization and alcohol release from alkyl-substituted benzoyl benzoic esters","year":2011,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Radical Photochemical Reactions","field":"Chemistry","cited_by":6,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Victoria","funders":"","keywords":"Chemistry; Substituent; Flash photolysis; Alkyl; Photochemistry; Intersystem crossing; Isopropyl; Medicinal chemistry; Reactivity (psychology); Photodissociation; Organic chemistry; Reaction rate constant; Singlet state; Excited state","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00005904741,0.0001712218,0.0003622151,0.00005778205,0.00006773946,0.00002391236,0.0003001104,0.0002389904,0.002750132],"category_scores_gemma":[0.0004325263,0.0001802618,0.0001100595,0.0001241402,0.0002682522,0.000138645,0.00001365991,0.0004480422,0.00000300708],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001827991,"about_ca_system_score_gemma":0.0005942666,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.005054131,"about_ca_topic_score_gemma":0.0007813046,"domain_scores_codex":[0.998732,0.000008032296,0.0006193989,0.0001787393,0.0002078782,0.0002540064],"domain_scores_gemma":[0.9979337,0.00008143151,0.0004888455,0.0002582601,0.0001818565,0.001055868],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000503626,0.00006246827,0.02189874,0.00008790105,0.0001117789,0.00006433873,0.000733953,0.00001217802,0.9750152,0.000006972678,0.001106859,0.0008492499],"study_design_scores_gemma":[0.0006431964,0.00001052579,0.001574179,0.0002152609,0.0001006129,0.00006778358,0.0004207548,0.0001468991,0.9944128,0.0003527468,0.001884696,0.0001705711],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9872862,0.0007770751,0.00005366897,0.00004336453,0.00007048056,0.00003427959,0.00009954489,0.000009426312,0.01162595],"genre_scores_gemma":[0.9992653,0.00002270823,0.0003991819,0.00003385555,0.0001270041,0.000002560885,0.00004518331,0.00002299221,0.00008117352],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02032456,"threshold_uncertainty_score":0.9981615,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03840494671559589,"score_gpt":0.261087346094269,"score_spread":0.2226823993786732,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}