{"id":"W1974682569","doi":"10.1021/ol0708875","title":"Structurally Defined Imidazolium-Type Ionic Oligomers as Soluble/Solid Support for Peptide Synthesis","year":2007,"lang":"en","type":"article","venue":"Organic Letters","topic":"Ionic liquids properties and applications","field":"Chemical Engineering","cited_by":45,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University","funders":"","keywords":"Chemistry; Peptide; Ionic liquid; Homogeneous; Combinatorial chemistry; Reagent; Oligopeptide; Phase (matter); Peptide synthesis; Ionic bonding; Solid-phase synthesis; Organic chemistry; Catalysis; Ion; Biochemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0002354343,0.0002449765,0.000253326,0.00007351391,0.0001798428,0.00004367503,0.0003661339,0.0001211148,0.001087344],"category_scores_gemma":[0.0002457364,0.0002215522,0.0001345211,0.000252663,0.00005894631,0.000119752,0.00007757102,0.000189768,0.0003731931],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002554563,"about_ca_system_score_gemma":0.00009029005,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00004811164,"about_ca_topic_score_gemma":0.0000109007,"domain_scores_codex":[0.9983425,0.000008315291,0.0003996251,0.0003609317,0.0002040796,0.000684579],"domain_scores_gemma":[0.9990395,0.0002183391,0.00009069946,0.0004100626,0.00007644708,0.0001649946],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005667448,0.00001627125,0.00001980537,0.00004328602,0.00007232317,0.000004697541,0.0001496563,0.0001774031,0.9904503,0.001937659,0.006479747,0.0005921539],"study_design_scores_gemma":[0.0005045054,0.00005927895,0.0001319444,0.00002672308,0.00009278545,0.00004640815,0.0001383992,0.0008385745,0.9837877,0.0001222178,0.01379557,0.0004559359],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9801914,0.00004073621,0.0109216,0.006488582,0.0005285076,0.0004250567,0.00001013193,0.0003264897,0.001067457],"genre_scores_gemma":[0.9930018,0.00001543191,0.002702314,0.002913896,0.0003670449,0.00004827226,0.00003644468,0.00009606607,0.0008186975],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0128104,"threshold_uncertainty_score":0.9998258,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01064476221801708,"score_gpt":0.2335957596498972,"score_spread":0.2229509974318801,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}