{"id":"W1974798756","doi":"10.1021/om010510h","title":"Dinuclear Trivalent and Mixed-Valence Uranium [(−CH<sub>2</sub>−)<sub>5</sub>]<sub>4</sub>-calix[4]tetrapyrrole Complexes with Short Intermetallic Distances","year":2001,"lang":"en","type":"article","venue":"Organometallics","topic":"Radioactive element chemistry and processing","field":"Chemistry","cited_by":35,"is_retracted":false,"has_abstract":true,"ca_institutions":"Memorial University of Newfoundland; University of Ottawa","funders":"","keywords":"Chemistry; Tetrapyrrole; Uranium; Valence (chemistry); Intermetallic; Crystallography; Antiferromagnetism; Actinide; Metal; Inorganic chemistry; Stereochemistry; Condensed matter physics; Organic chemistry; Metallurgy","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":["metaepi_narrow"],"category_scores_codex":[0.0004930181,0.001290573,0.001284683,0.0002109187,0.0008278547,0.0005921302,0.001023644,0.0004676396,0.0003204846],"category_scores_gemma":[0.0001295707,0.001228603,0.0003720228,0.001107396,0.001071374,0.001065379,0.0003163907,0.001134618,0.00007844339],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003897039,"about_ca_system_score_gemma":0.0001856697,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000006038571,"about_ca_topic_score_gemma":0.00007825468,"domain_scores_codex":[0.9942157,0.0001151503,0.001184757,0.00181045,0.001201358,0.001472599],"domain_scores_gemma":[0.9970012,0.0003053407,0.000588363,0.001101454,0.0002878681,0.000715774],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000474284,0.0005230971,0.006669581,0.0009483264,0.0005685101,0.000161051,0.0003989846,0.00003094416,0.954117,0.00008497786,0.0002799472,0.03574328],"study_design_scores_gemma":[0.001515151,0.0001829776,0.00333255,0.0004807826,0.0004972954,0.0003392922,0.0008805129,0.0002182865,0.9817445,0.0002526997,0.008997595,0.001558385],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9921646,0.002128021,0.001011624,0.0002480663,0.0002178592,0.0003549699,0.000279199,0.0003936948,0.003202035],"genre_scores_gemma":[0.9924005,0.005665391,0.0002980985,0.0001819718,0.0005928043,0.00008248528,0.0003759468,0.0002587456,0.00014407],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0341849,"threshold_uncertainty_score":0.9999846,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01360048908757634,"score_gpt":0.2228449747787674,"score_spread":0.2092444856911911,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}