{"id":"W1974798756","doi":"10.1021/om010510h","title":"Dinuclear Trivalent and Mixed-Valence Uranium [(−CH<sub>2</sub>−)<sub>5</sub>]<sub>4</sub>-calix[4]tetrapyrrole Complexes with Short Intermetallic Distances","year":2001,"lang":"en","type":"article","venue":"Organometallics","topic":"Radioactive element chemistry and processing","field":"Chemistry","cited_by":35,"is_retracted":false,"has_abstract":true,"ca_institutions":"Memorial University of Newfoundland; University of Ottawa","funders":"","keywords":"Chemistry; Tetrapyrrole; Uranium; Valence (chemistry); Intermetallic; Crystallography; Antiferromagnetism; Actinide; Metal; Inorganic chemistry; Stereochemistry; Condensed matter physics; Organic chemistry; Metallurgy","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001651131,0.0002359661,0.0002620124,0.000166706,0.0003053224,0.0005203888,0.0005680388,0.0002661448,0.001026978],"category_scores_gemma":[0.0002891248,0.0001888902,0.00007607121,0.0001780138,0.0002305333,0.0002194444,0.0003268372,0.0002748386,0.000167197],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004608095,"about_ca_system_score_gemma":0.0001335323,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005471545,"about_ca_topic_score_gemma":0.001116211,"domain_scores_codex":[0.9998546,0.00002674074,0.000008843612,0.00003041872,0.0000458666,0.00003356562],"domain_scores_gemma":[0.9998941,0.00001686597,0.00002628809,0.00001385693,0.00001927205,0.00002947613],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0007539937,0.00006159013,0.0006358559,0.0002158172,0.00003633922,0.0001116773,0.00009460942,0.0005714203,0.9912016,0.001947799,0.0002055471,0.004163609],"study_design_scores_gemma":[0.00006601527,0.0004777389,0.001315988,0.000007324795,0.00002972441,0.0002468242,0.00005403451,0.002138556,0.9931591,0.0001721826,0.00232082,0.00001168456],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9965984,0.0004771044,0.00098726,0.00002696681,0.00001137282,0.00001071907,0.00004890833,0.00002667212,0.00181247],"genre_scores_gemma":[0.9976124,0.0001549113,0.001222334,0.00001163387,0.000001756786,0.0000073656,0.00009052377,0.000009479885,0.0008897231],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001026978,"threshold_uncertainty_score":0.003435612,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01360048908757634,"score_gpt":0.2228449747787674,"score_spread":0.2092444856911911,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}