{"id":"W1974842184","doi":"10.1039/b412111b","title":"Multiple functional group cooperation in phosphate diester cleavage promoted by Zn(ii) complexes","year":2004,"lang":"en","type":"article","venue":"Chemical Communications","topic":"Chemical Synthesis and Characterization","field":"Environmental Science","cited_by":62,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Cleavage (geology); Chemistry; Phosphate; Group (periodic table); Medicinal chemistry; Stereochemistry; Organic chemistry; Materials science","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00009242888,0.0001211532,0.0001239683,0.00001399885,0.0002192453,0.00003262415,0.0004001131,0.00008790146,0.00036232],"category_scores_gemma":[0.00009133874,0.0001178959,0.00003908447,0.000240231,0.0002532844,0.0002456074,0.0004614746,0.0001950356,0.0001361241],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002541456,"about_ca_system_score_gemma":0.000005853743,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001912338,"about_ca_topic_score_gemma":0.0001568474,"domain_scores_codex":[0.9991259,0.00003474117,0.0002783896,0.0002288539,0.000151679,0.0001804676],"domain_scores_gemma":[0.9992211,0.00008927996,0.00006564069,0.0005389028,0.00001038167,0.00007469601],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001468513,0.0005141527,0.004665863,0.000002672153,0.000003395515,1.282695e-7,0.0001627794,0.00002901952,0.992262,0.0002719253,0.000783758,0.001289607],"study_design_scores_gemma":[0.001066927,0.00002863079,0.03295854,0.00003770636,0.00001077466,0.000002825427,0.00003808381,0.001598893,0.939761,0.0009521054,0.02323875,0.0003057873],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9938782,0.0000685111,0.001074462,0.002569682,0.000020901,0.000235001,0.00002836891,0.00006305761,0.002061844],"genre_scores_gemma":[0.9967414,0.00005379197,0.001634427,0.0003420845,0.00001461375,0.00008982333,0.001026589,0.00001387778,0.0000834434],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.05250104,"threshold_uncertainty_score":0.4807656,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01994423264283195,"score_gpt":0.2195389546310258,"score_spread":0.1995947219881939,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}