{"id":"W1974842619","doi":"10.1021/om0606892","title":"Redox-Active, Multinuclear (Ferrocenylethynyl)phosphanes and Their Palladium and Platinum Complexes","year":2006,"lang":"en","type":"article","venue":"Organometallics","topic":"Metal-Organic Frameworks: Synthesis and Applications","field":"Chemistry","cited_by":27,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Calgary","funders":"Bundesministerium für Bildung und Forschung; Deutsche Forschungsgemeinschaft","keywords":"Chemistry; Palladium; Redox; Steric effects; Platinum; Electrochemistry; Acetylene; Structural motif; Crystallography; Stereochemistry; Polymer chemistry; Inorganic chemistry; Organic chemistry; Catalysis; Physical chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001017697,0.0003178016,0.0003902008,0.00005181255,0.0002694296,0.0001288027,0.0002039944,0.0002192644,0.002645277],"category_scores_gemma":[0.00008563586,0.0002720927,0.00006561034,0.0002114798,0.0002403263,0.0001132751,0.0001508614,0.0002554129,0.00004374368],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00002936892,"about_ca_system_score_gemma":0.00002078417,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00009040077,"about_ca_topic_score_gemma":0.00003962028,"domain_scores_codex":[0.9986545,0.0000181937,0.0003486807,0.00049755,0.0001466005,0.000334485],"domain_scores_gemma":[0.9989548,0.0002519374,0.0001697793,0.0004304689,0.00005623008,0.000136733],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000276427,0.000229564,0.00243614,0.0001507316,0.0001122767,0.000003955051,0.0004982281,0.0000054885,0.9698272,0.009476919,0.0007942651,0.01643761],"study_design_scores_gemma":[0.001048436,0.00003628014,0.02583292,0.0001002013,0.0001367578,0.00007749457,0.00186309,0.001245007,0.7111305,0.006233684,0.2512176,0.001078078],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.985951,0.001472415,0.0003021708,0.0006150734,0.00003456939,0.000123819,0.0001159787,0.0001602026,0.01122479],"genre_scores_gemma":[0.9939832,0.00035308,0.002843253,0.000106398,0.0001968062,0.00002114075,0.00006911885,0.00007692738,0.002350076],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.2586967,"threshold_uncertainty_score":0.9999731,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01146405000010101,"score_gpt":0.2127325124415875,"score_spread":0.2012684624414865,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}