{"id":"W1974875958","doi":"10.1139/cjc-2014-0107","title":"Triazene derivatives of (1,<i>x</i>)-diazacycloalkanes. Part X. Synthesis and characterization of a series of 1,4-di[2-aryl-1-diazenyl]-<i>trans</i>-2,5-dimethylpiperazines","year":2014,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Chemical Reactions and Mechanisms","field":"Chemistry","cited_by":10,"is_retracted":false,"has_abstract":true,"ca_institutions":"Saint Mary's University","funders":"","keywords":"Chemistry; Triazene; Piperazine; Stereocenter; Methylene; Aryl; Ring (chemistry); Mass spectrum; Azole; Stereochemistry; Heteronuclear single quantum coherence spectroscopy; Proton NMR; Spectroscopy; Mass spectrometry; Carbon-13 NMR; Nuclear magnetic resonance spectroscopy; Medicinal chemistry; Ion; Organic chemistry; Alkyl; Enantioselective synthesis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002492894,0.0002124496,0.0006775519,0.00009330472,0.00004714231,0.00001506712,0.0002476193,0.0002099247,0.0005746626],"category_scores_gemma":[0.0006912887,0.000205747,0.0001884619,0.0001780851,0.0002944313,0.0001798689,0.00001521716,0.0002066368,1.760389e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00004385436,"about_ca_system_score_gemma":0.0004575633,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002622285,"about_ca_topic_score_gemma":0.00007072989,"domain_scores_codex":[0.9984809,0.00001771133,0.0008755519,0.0001708072,0.0002179072,0.0002371264],"domain_scores_gemma":[0.9978001,0.0002257757,0.0008946517,0.0002673268,0.0003953694,0.0004168117],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008639574,0.00004196406,0.0009384258,0.0008152337,0.0001006022,0.000005448111,0.0002713869,0.000004413171,0.9946244,0.00002857319,0.00003956563,0.003043619],"study_design_scores_gemma":[0.0005192591,0.00003356235,0.0003214266,0.0005689115,0.0001094447,0.0001123673,0.0002506962,0.00001516656,0.9905577,0.0001926015,0.007152453,0.000166436],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9972098,0.00032846,0.0001430657,0.0002027386,0.00007638834,0.00003591924,0.0002002958,0.000005819726,0.001797466],"genre_scores_gemma":[0.9989635,0.0003233145,0.0002582472,0.00001589761,0.0001720748,0.000004446553,0.00002240135,0.00002745787,0.0002126376],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.007112887,"threshold_uncertainty_score":0.8390121,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008112487699364556,"score_gpt":0.1907915682817623,"score_spread":0.1826790805823977,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}