{"id":"W1975003088","doi":"10.1002/chin.200142063","title":"ChemInform Abstract: A Deep Seated Carbodication Rearrangement. Limited Paths Because of Charge Repulsion.","year":2001,"lang":"en","type":"article","venue":"ChemInform","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Calgary","funders":"","keywords":"Chemistry; Charge (physics); Service (business); Quantum mechanics; Business; Marketing; Physics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.000199908,0.0003119926,0.0003490378,0.0001261332,0.0001382695,0.00006154925,0.0003714353,0.0003262313,0.007995699],"category_scores_gemma":[0.0003815313,0.000324562,0.0001991107,0.00045421,0.0001540109,0.0003662929,0.0001173996,0.0003395566,0.0002149458],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003565316,"about_ca_system_score_gemma":0.0001098158,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002094016,"about_ca_topic_score_gemma":0.00001876496,"domain_scores_codex":[0.9978543,6.734298e-9,0.0008184513,0.0003569623,0.0004946867,0.0004756044],"domain_scores_gemma":[0.9977975,0.00009918607,0.0005450444,0.001055771,0.0002889164,0.0002135997],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001115542,0.0002303041,0.000668155,0.0003184844,0.0001048535,0.00001447241,0.001251311,6.956553e-7,0.8353439,0.00001961052,0.01005703,0.1518797],"study_design_scores_gemma":[0.0009516616,0.00001276526,0.002356005,0.0001364129,0.00008510805,0.00004899198,0.0005342576,0.0001902884,0.9499908,0.00001272716,0.0453417,0.0003392484],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.5796006,0.00008852471,1.172897e-7,0.00007774645,0.00008288275,0.0001312766,0.00005713167,0.000210408,0.4197513],"genre_scores_gemma":[0.9565602,0.0002275973,0.000007166805,0.00004447398,0.000177423,0.00007884301,0.001312584,0.0000475916,0.04154414],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.3782072,"threshold_uncertainty_score":0.9999207,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01783871584148814,"score_gpt":0.2605076442735863,"score_spread":0.2426689284320982,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}