{"id":"W1975125835","doi":"10.1002/adsc.201200053","title":"Synthesis of Alcohols <i>via</i> a Rhodium‐Catalyzed Hydroformylation– Reduction Sequence using Tertiary Bidentate Amine Ligands","year":2012,"lang":"en","type":"article","venue":"Advanced Synthesis & Catalysis","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":45,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"","keywords":"Hydroformylation; Chemistry; Rhodium; Denticity; Aldehyde; Olefin fiber; Ligand (biochemistry); Catalysis; Organic chemistry; Alkyl; Amine gas treating; Combinatorial chemistry; Medicinal chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0007196872,0.0005418494,0.00094724,0.0007779541,0.000313982,0.00004560806,0.0005720092,0.0002606964,0.0006759943],"category_scores_gemma":[0.001035391,0.0005476188,0.0006495918,0.002130356,0.0002385692,0.001650767,0.0001612563,0.0002198956,0.0001177936],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000423631,"about_ca_system_score_gemma":0.00007844108,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003239717,"about_ca_topic_score_gemma":0.000009419959,"domain_scores_codex":[0.9962596,0.00006874789,0.00127313,0.0007193029,0.0008806944,0.0007984896],"domain_scores_gemma":[0.9964629,0.0006346431,0.001041805,0.001256848,0.000246996,0.0003568391],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007667784,0.0002865666,0.003893778,0.0001374538,0.0005957675,0.000004195481,0.000355087,0.0007884718,0.8910422,0.00001093583,0.00001489965,0.1027939],"study_design_scores_gemma":[0.000288814,0.000004870924,0.0003431563,0.0001306007,0.001514289,0.00008351731,0.0006469809,0.002882812,0.9931799,0.00004224047,0.0002925012,0.0005903254],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9924448,0.001095472,0.003574037,0.000100561,0.0001455035,0.0001706233,0.0001496785,0.0002133096,0.002106032],"genre_scores_gemma":[0.9952519,0.0003196135,0.003240437,0.00003282546,0.0002165237,0.0002207211,0.0002977777,0.000100193,0.0003200211],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1022036,"threshold_uncertainty_score":0.9996975,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02106064721777469,"score_gpt":0.2766162628700225,"score_spread":0.2555556156522478,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}