{"id":"W1975145348","doi":"10.1021/jo800670t","title":"Reactive Extraction of Enantiomers of 1,2-Amino Alcohols via Stereoselective Thermodynamic and Kinetic Processes","year":2008,"lang":"en","type":"article","venue":"The Journal of Organic Chemistry","topic":"Analytical Chemistry and Chromatography","field":"Chemistry","cited_by":37,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Chemistry; Stereoselectivity; Enantiomer; Kinetic resolution; Extraction (chemistry); Kinetic energy; Organic chemistry; Chromatography; Enantioselective synthesis; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001643163,0.0001872723,0.000390348,0.00003042581,0.0000695401,0.000004758261,0.0002898103,0.0001453074,0.0006587342],"category_scores_gemma":[0.0001748045,0.0001335015,0.0001222671,0.0003353668,0.0004540812,0.0001127147,0.00004231874,0.0003951574,5.780095e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00004925191,"about_ca_system_score_gemma":0.0001759789,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000008097329,"about_ca_topic_score_gemma":6.692723e-7,"domain_scores_codex":[0.9987688,0.0000177006,0.0005713431,0.0001319618,0.0003406159,0.000169582],"domain_scores_gemma":[0.9979997,0.0002914141,0.0009945309,0.0002246916,0.0004019742,0.00008771416],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002171211,0.0001749005,0.00189363,0.0007411838,0.0002795899,0.00001367768,0.0005958551,0.000003175633,0.995917,8.081172e-7,0.00001831949,0.000144755],"study_design_scores_gemma":[0.0005623344,0.00004556425,0.001647409,0.0001921963,0.00027454,0.002235661,0.001062272,0.00003718411,0.9936072,0.0001892721,0.00001906888,0.000127322],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9949083,0.000780977,0.0003734553,0.0000328792,0.00001173601,0.00002840198,0.0000093078,0.00000872271,0.003846158],"genre_scores_gemma":[0.9990704,0.0005749734,0.00005713602,0.000005211676,0.00008203914,7.47196e-7,0.000002948085,0.00002063769,0.0001858773],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.004162068,"threshold_uncertainty_score":0.7212677,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00878007043573692,"score_gpt":0.2239273452087668,"score_spread":0.2151472747730299,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}