{"id":"W1975225758","doi":"10.1021/ja808517d","title":"Probing the Mechanism of the PCl<sub>5</sub>−Initiated Living Cationic Polymerization of the Phosphoranimine Cl<sub>3</sub>P═NSiMe<sub>3</sub> using Model Compound Chemistry","year":2009,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":54,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Chemistry; Cationic polymerization; Polymerization; Mechanism (biology); Polymer chemistry; Stereochemistry; Medicinal chemistry; Organic chemistry; Polymer","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001356012,0.0002770511,0.0001089531,0.00007028851,0.000143603,0.0002260853,0.0002457821,0.0003807919,0.001438128],"category_scores_gemma":[0.0001517937,0.0001197914,0.000207789,0.00005602301,0.0004048617,0.0004062558,0.0002243573,0.000487402,0.0003874135],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004460891,"about_ca_system_score_gemma":0.0002772117,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004007791,"about_ca_topic_score_gemma":0.0004034873,"domain_scores_codex":[0.9999267,0.00000940238,0.000004125277,0.00001801455,0.00002273911,0.00001893773],"domain_scores_gemma":[0.9999168,0.00001934955,0.000030173,0.000007159052,0.00001290195,0.00001371748],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002720964,0.000005961867,0.00008164172,0.00003464783,0.000001293669,0.00004999433,0.00002800552,0.0001383585,0.9986389,0.0003412791,0.00001176536,0.0006408084],"study_design_scores_gemma":[0.000005260095,0.00007489221,0.0004283795,0.000001705821,0.000001645362,0.00006418805,0.00001243037,0.000789935,0.9980732,0.00007372845,0.0004711585,0.000003421278],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9915181,0.0004634844,0.006019739,0.00007313568,0.00001052221,0.00003595584,0.00008962992,0.00009229402,0.001697053],"genre_scores_gemma":[0.9959593,0.0002500643,0.002419257,0.00002883645,0.000003900992,0.0000242328,0.00004638041,0.00001321723,0.001254659],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001438128,"threshold_uncertainty_score":0.004811049,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01610591038128077,"score_gpt":0.2226242581048305,"score_spread":0.2065183477235498,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}