{"id":"W1975242451","doi":"10.1016/j.tet.2011.07.088","title":"Preparation of chiral secondary boronic esters via copper-catalyzed enantioselective conjugate reduction of β-boronyl-β-alkyl α,β-unsaturated esters","year":2011,"lang":"en","type":"article","venue":"Tetrahedron","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":22,"is_retracted":false,"has_abstract":false,"ca_institutions":"University of Alberta","funders":"","keywords":"Chemistry; Enantioselective synthesis; Conjugate; Alkyl; Copper; Catalysis; Organic chemistry; Combinatorial chemistry; Hydride; Metal","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003520786,0.0007577289,0.0004950096,0.0004281966,0.0002872416,0.0003439992,0.0005114924,0.0003490589,0.003206983],"category_scores_gemma":[0.000228416,0.0002943052,0.0003876197,0.0003441136,0.0002475456,0.0004448044,0.0005466726,0.0006963989,0.00173595],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004466733,"about_ca_system_score_gemma":0.000599996,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0008913526,"about_ca_topic_score_gemma":0.001765389,"domain_scores_codex":[0.9997855,0.00002526766,0.00001796646,0.00002651194,0.00004642202,0.00009836094],"domain_scores_gemma":[0.9999204,0.00000750667,0.00001490768,0.00001261839,0.00001774947,0.00002684128],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0004402474,0.0001480149,0.0001979118,0.0003198656,0.00004808902,0.0008330235,0.0001989806,0.001052166,0.9754719,0.003279004,0.0009305842,0.01708003],"study_design_scores_gemma":[0.00003976896,0.0001549057,0.0001548566,0.000006037242,0.00001312733,0.0001407863,0.00001751688,0.0002993601,0.9955673,0.0001424937,0.003453814,0.00001005068],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8997214,0.002491795,0.04365417,0.0004921255,0.0003264759,0.0004071934,0.001206712,0.0005693766,0.05113076],"genre_scores_gemma":[0.9800163,0.001769949,0.007440437,0.0001033021,0.00003618546,0.00007385073,0.0004489126,0.00008220609,0.01002893],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003206983,"threshold_uncertainty_score":0.01072836,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01224661271424896,"score_gpt":0.2473770270013273,"score_spread":0.2351304142870783,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}