{"id":"W1975259361","doi":"10.1016/j.tet.2011.01.083","title":"Convergent stereoselective and efficient synthesis of furanic-steroid derivatives","year":2011,"lang":"en","type":"article","venue":"Tetrahedron","topic":"Synthetic Organic Chemistry Methods","field":"Chemistry","cited_by":11,"is_retracted":false,"has_abstract":false,"ca_institutions":"Université Laval","funders":"Canadian Institutes of Health Research; Canadian Breast Cancer Research Alliance; Breast Cancer Alliance","keywords":"Chemistry; Stereoselectivity; Steroid; Convergent synthesis; Organic chemistry; Combinatorial chemistry; Stereochemistry; Catalysis; Hormone; Biochemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002646995,0.0003854581,0.0002930449,0.0002646864,0.000330525,0.0002560448,0.000409555,0.0002330901,0.002660198],"category_scores_gemma":[0.0001516253,0.0001696469,0.0001603884,0.0002868719,0.0002975511,0.0002523359,0.0004053921,0.0006202364,0.001451751],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0006264932,"about_ca_system_score_gemma":0.0009281713,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001702329,"about_ca_topic_score_gemma":0.006396265,"domain_scores_codex":[0.9998012,0.00002643044,0.0000127955,0.00002997319,0.00005862009,0.00007096835],"domain_scores_gemma":[0.999943,0.000006946395,0.000009313379,0.00001342235,0.00001310307,0.00001420224],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002333173,0.0001246867,0.0002960913,0.0002445636,0.00002533508,0.0008486591,0.0003250416,0.001460718,0.9459401,0.01491885,0.001304301,0.03427828],"study_design_scores_gemma":[0.00005257709,0.000237269,0.0005711774,0.00001768126,0.00001909413,0.0003519238,0.00005806925,0.0007720229,0.9680929,0.00090842,0.02889948,0.00001939745],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8301669,0.005779715,0.06060877,0.00074306,0.0003999172,0.0002957695,0.001434451,0.0005404167,0.100031],"genre_scores_gemma":[0.9662191,0.00258837,0.01385345,0.00008581748,0.00003145985,0.00004669594,0.0002897351,0.00006821409,0.0168171],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002660198,"threshold_uncertainty_score":0.008899212,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02818115659804724,"score_gpt":0.2464054712068254,"score_spread":0.2182243146087781,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}