{"id":"W1975327976","doi":"10.1021/ic034430c","title":"Structures and Conformational Dynamics of Gold(I) Halide Complexes of Resorcinarene Tetraphosphinite Ligands","year":2003,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Supramolecular Chemistry and Complexes","field":"Chemistry","cited_by":15,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"","keywords":"Resorcinarene; Chemistry; Conformational isomerism; Intramolecular force; Halide; Cyclohexane conformation; Calixarene; Crystallography; Supramolecular chemistry; Stereochemistry; Computational chemistry; Molecule; Organic chemistry; Crystal structure; Hydrogen bond","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00008098046,0.0001653974,0.0001838,0.0001065413,0.0001413461,0.0002967468,0.0003685786,0.000180904,0.001431431],"category_scores_gemma":[0.0003034446,0.0001532739,0.00008001349,0.00009702359,0.0002622228,0.0002319656,0.0001208471,0.0003201392,0.0001546263],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005642142,"about_ca_system_score_gemma":0.0001260337,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00146193,"about_ca_topic_score_gemma":0.001694167,"domain_scores_codex":[0.9999399,0.000007557805,0.000002375191,0.00001631703,0.00001741633,0.00001647166],"domain_scores_gemma":[0.9998833,0.00003243137,0.00003006675,0.00000983859,0.00001854365,0.00002582234],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002509565,0.00002930312,0.0006453905,0.00003724605,0.00001744687,0.0001021365,0.0001425474,0.002554979,0.9928786,0.001019561,0.00008621284,0.002235638],"study_design_scores_gemma":[0.00004538586,0.000290143,0.003994562,0.000006908644,0.00001767706,0.0001270927,0.00008295621,0.01615006,0.9778687,0.0002410031,0.001154383,0.00002106145],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9987674,0.00009218518,0.0005072674,0.0000136604,0.000001671974,0.000003074132,0.0000318176,0.00001176058,0.0005711301],"genre_scores_gemma":[0.9985706,0.00008880876,0.0004912678,0.00001073688,9.935974e-7,0.000005392539,0.0001176973,0.000009739822,0.0007048309],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00146193,"threshold_uncertainty_score":0.004788637,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007589331965019299,"score_gpt":0.2108594194997631,"score_spread":0.2032700875347438,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}