{"id":"W1975639820","doi":"10.1016/j.jhazmat.2008.07.102","title":"Kinetics of transformation of 1,1,1-trichloroethane by Fe(II) in cement slurries","year":2008,"lang":"en","type":"article","venue":"Journal of Hazardous Materials","topic":"Environmental remediation with nanomaterials","field":"Engineering","cited_by":8,"is_retracted":false,"has_abstract":false,"ca_institutions":"University of Toronto","funders":"","keywords":"Portland cement; Slurry; Chemistry; Degradation (telecommunications); Cement; Kinetics; Reaction rate constant; Saturation (graph theory); Biodegradation; Nuclear chemistry; Hydrogenolysis; Inorganic chemistry; Metallurgy; Organic chemistry; Catalysis; Materials science","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003177938,0.0001304332,0.0005042669,0.0001984896,0.0000133828,0.00000692495,0.0001336347,0.00007793864,0.0002313634],"category_scores_gemma":[0.00004000738,0.0001179859,0.00005433484,0.00009954412,0.00005624942,0.0002152685,0.00001625779,0.00004633717,0.000003498772],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00009204274,"about_ca_system_score_gemma":0.00001190831,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000008432713,"about_ca_topic_score_gemma":0.000001676602,"domain_scores_codex":[0.9980286,0.00005195989,0.001359821,0.00005196442,0.0003607092,0.0001469578],"domain_scores_gemma":[0.9992945,0.00003429097,0.0004783544,0.00009907041,0.00004689123,0.00004686915],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008830662,0.00009570199,0.0002490623,0.000169024,0.00003077654,0.000005733601,0.001051241,0.00271602,0.9950157,0.0000093058,0.0004199898,0.0001491723],"study_design_scores_gemma":[0.001009593,0.0003152291,0.003424085,0.00008341599,0.00002094795,0.00005227649,0.00007616333,0.00001410479,0.9941975,0.00003202507,0.0006814737,0.00009311576],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.998248,0.0003703593,0.0003496073,0.00004726821,0.0006265129,0.0001561537,0.00008699117,0.00001039438,0.0001046643],"genre_scores_gemma":[0.9978373,0.001369241,0.0006712812,0.000008472482,0.00006116214,0.000003581133,0.00001242259,0.00002069576,0.00001585381],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003175022,"threshold_uncertainty_score":0.4811327,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008549489068421423,"score_gpt":0.1965885713349592,"score_spread":0.1880390822665378,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}