{"id":"W1975755418","doi":"10.1021/om0302084","title":"Concise Route to Highly Reactive Ruthenium Metathesis Catalysts Containing a Labile Donor and an N-Heterocyclic Carbene (NHC) Ligand","year":2003,"lang":"en","type":"article","venue":"Organometallics","topic":"Synthetic Organic Chemistry Methods","field":"Chemistry","cited_by":39,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"","keywords":"Chemistry; Carbene; Phosphine; Ligand (biochemistry); IMes; Lability; Olefin metathesis; Metathesis; Catalysis; Ruthenium; Combinatorial chemistry; Stoichiometry; Umpolung; Olefin fiber; Medicinal chemistry; Salt metathesis reaction; Organic chemistry; Nucleophile; Polymerization","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002771069,0.0009198385,0.0005198058,0.0003707325,0.000385113,0.0003813683,0.0008733065,0.0004060684,0.004079765],"category_scores_gemma":[0.0001621709,0.0004746104,0.0002492943,0.0002071763,0.0002729924,0.0005687843,0.0004304024,0.001238613,0.001936559],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004968659,"about_ca_system_score_gemma":0.0006866549,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004471716,"about_ca_topic_score_gemma":0.001578214,"domain_scores_codex":[0.9998319,0.00002205623,0.00002037768,0.00003332163,0.00005686567,0.00003548396],"domain_scores_gemma":[0.999925,0.00001088463,0.00002190293,0.00001228383,0.000009924684,0.00001997532],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001681183,0.0004263658,0.0001185592,0.0006651706,0.00004804384,0.000916476,0.0002089245,0.002663117,0.9354054,0.01831657,0.006550574,0.0345126],"study_design_scores_gemma":[0.0002561953,0.001176683,0.0005694377,0.00003309713,0.00005132993,0.0009811549,0.0000450617,0.002767654,0.9208716,0.003246433,0.06995092,0.00005035844],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.6050075,0.01173251,0.2782746,0.00299429,0.001331558,0.001314555,0.004399908,0.007419707,0.08752542],"genre_scores_gemma":[0.9250821,0.004725934,0.05004003,0.0002174856,0.0001123396,0.0003487682,0.001701895,0.0002587681,0.01751249],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.004079765,"threshold_uncertainty_score":0.01364815,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01962004630670052,"score_gpt":0.2761476670576119,"score_spread":0.2565276207509114,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}