{"id":"W1975784306","doi":"10.1021/ef050081q","title":"Detailed Kinetic Modeling of Carbonaceous Nanoparticle Inception and Surface Growth during the Pyrolysis of C<sub>6</sub>H<sub>6</sub> behind Shock Waves","year":2006,"lang":"en","type":"article","venue":"Energy & Fuels","topic":"Advanced Combustion Engine Technologies","field":"Chemical Engineering","cited_by":41,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia; McMaster University; University of Toronto; University of New Brunswick","funders":"","keywords":"Soot; Nucleation; Combustion; Particle (ecology); Materials science; Aerosol; Carbon fibers; Pyrolysis; Nanoparticle; Supersaturation; Chemical engineering; Thermodynamics; Chemistry; Chemical physics; Nanotechnology; Physical chemistry; Organic chemistry; Physics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0001155985,0.0002834567,0.0003930247,0.0001277217,0.0000854744,0.00001523906,0.0002549075,0.0001665947,0.000002319225],"category_scores_gemma":[0.0001204988,0.0002515111,0.0001114406,0.0003639846,0.0001957664,0.0001716086,0.0001875833,0.000222583,0.000001395123],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00008482163,"about_ca_system_score_gemma":0.00001461553,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00009438305,"about_ca_topic_score_gemma":0.00008738938,"domain_scores_codex":[0.9983338,0.00003678049,0.0005757699,0.0003534391,0.0003109489,0.0003893157],"domain_scores_gemma":[0.9990621,0.000134497,0.0001927477,0.0004287092,0.0001278984,0.00005403039],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001591812,0.00002415031,0.0002219658,0.00003999921,0.00002321123,0.000002246579,0.00004603805,0.4584854,0.5399034,0.0007630635,7.814656e-7,0.0004737863],"study_design_scores_gemma":[0.0003863841,0.0000297756,0.0005940688,0.00004995969,0.00005149831,0.00000639061,0.0001034466,0.1954329,0.8012389,0.00190244,0.000001568781,0.000202652],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9767349,0.001037546,0.02163944,0.00007721433,0.00004577031,0.00009141616,0.000007589028,0.0003030222,0.00006304846],"genre_scores_gemma":[0.9987661,0.0002682215,0.0008089109,0.000006462712,0.00004817967,0.00002246732,0.00000712175,0.00005573708,0.00001682878],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.2630525,"threshold_uncertainty_score":0.9999937,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.004935348399509695,"score_gpt":0.1788241816976024,"score_spread":0.1738888332980927,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}