{"id":"W1975879873","doi":"10.1002/elps.200500583","title":"Enhanced binding and conformational selectivity in affinity capillary electrophoresis using a water‐soluble resorcin[4]arene as intrinsic buffer and electrokinetic host","year":2006,"lang":"en","type":"article","venue":"Electrophoresis","topic":"Microfluidic and Capillary Electrophoresis Applications","field":"Engineering","cited_by":3,"is_retracted":false,"has_abstract":true,"ca_institutions":"McMaster University","funders":"","keywords":"Chemistry; Capillary electrophoresis; Electrokinetic phenomena; Selectivity; Buffer (optical fiber); Electrophoresis; Micellar electrokinetic chromatography; Buffer solution; Electrolyte; Hydrophobic effect; Enthalpy; Chromatography; Analytical Chemistry (journal); Physical chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0003242168,0.0005770985,0.0006223604,0.0006641223,0.0003898782,0.0001703748,0.0002244171,0.000293422,0.0001193994],"category_scores_gemma":[0.00003418682,0.0005624293,0.00008792461,0.0009721835,0.0001474622,0.0002715012,0.00008844429,0.000596266,0.00002695879],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005426867,"about_ca_system_score_gemma":0.0001386651,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0009625336,"about_ca_topic_score_gemma":0.0003005938,"domain_scores_codex":[0.9968173,0.0001251699,0.000672977,0.0006617247,0.0003795784,0.001343255],"domain_scores_gemma":[0.9991224,0.0001252697,0.00008739004,0.0003688522,0.0001131359,0.0001829391],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000130502,0.00006256743,0.0005701946,0.00007900644,0.00006535139,0.00001291414,0.0001524193,0.00007316117,0.9948724,0.001593309,0.002009693,0.0003785165],"study_design_scores_gemma":[0.0009155725,0.0002377563,0.01071935,0.00003668672,0.00007596208,0.000172715,0.000032274,0.001554802,0.9814226,0.001834944,0.00228225,0.0007151058],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9662796,0.03096164,0.0007708262,0.0001072994,0.00005313553,0.0005850116,0.00001215711,0.0002305524,0.0009997761],"genre_scores_gemma":[0.959945,0.03924598,0.0001761237,0.00005410499,0.0001380359,0.0001260479,0.00009453188,0.0001015053,0.0001187008],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01344978,"threshold_uncertainty_score":0.9996827,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.004070773575780231,"score_gpt":0.187741324822023,"score_spread":0.1836705512462427,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}