{"id":"W1975898567","doi":"10.1021/om000982g","title":"Monomeric Alkali Metal (Li, Na, K) Complexes of Bis(iminophosphorano)methanides","year":2001,"lang":"en","type":"article","venue":"Organometallics","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":65,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"","keywords":"Chemistry; Alkali metal; Methyllithium; Monomer; Ligand (biochemistry); Lithium (medication); Metal; Crystal structure; Solvent; Medicinal chemistry; Potassium; Yield (engineering); Coordination sphere; Crystallography; Inorganic chemistry; Stereochemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001192265,0.0003111031,0.0002684765,0.0001279749,0.0002311011,0.0004080099,0.0005009489,0.0002057669,0.001474599],"category_scores_gemma":[0.0002679361,0.0002668458,0.0001358247,0.000147568,0.0002026796,0.0002524786,0.0003662914,0.0004175876,0.0004550076],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0006785557,"about_ca_system_score_gemma":0.0002510037,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00151551,"about_ca_topic_score_gemma":0.002918159,"domain_scores_codex":[0.999822,0.00002664365,0.00001321132,0.00003502899,0.00005661079,0.00004652673],"domain_scores_gemma":[0.9999381,0.000006808584,0.00001219875,0.000007551847,0.00001094462,0.00002441095],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002639489,0.00002803957,0.0002998895,0.0001460462,0.00002048765,0.0001181042,0.0001141107,0.0003534014,0.9948507,0.001408773,0.0002713965,0.002125008],"study_design_scores_gemma":[0.00003567936,0.0001010656,0.0005525059,0.000006971133,0.00001792841,0.0001418336,0.00003896721,0.0007098253,0.9945569,0.0001011271,0.003731363,0.00000587091],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9881086,0.001490251,0.002560703,0.0001231604,0.00004349354,0.00003632043,0.0001173437,0.000181011,0.007339263],"genre_scores_gemma":[0.9926047,0.0005479631,0.001550644,0.00003269805,0.0000120205,0.00001843041,0.0001915939,0.00002958991,0.005012191],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00151551,"threshold_uncertainty_score":0.004933,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02143482337092898,"score_gpt":0.2315367350463901,"score_spread":0.2101019116754611,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}