{"id":"W1975898567","doi":"10.1021/om000982g","title":"Monomeric Alkali Metal (Li, Na, K) Complexes of Bis(iminophosphorano)methanides","year":2001,"lang":"en","type":"article","venue":"Organometallics","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":65,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"","keywords":"Chemistry; Alkali metal; Methyllithium; Monomer; Ligand (biochemistry); Lithium (medication); Metal; Crystal structure; Solvent; Medicinal chemistry; Potassium; Yield (engineering); Coordination sphere; Crystallography; Inorganic chemistry; Stereochemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0003404218,0.0005879946,0.001242707,0.0003570114,0.0001889644,0.0000870382,0.001006212,0.0002097958,0.1182192],"category_scores_gemma":[0.0001799069,0.0005667588,0.0006561513,0.001639599,0.0003586313,0.0002927684,0.0003276869,0.0002625907,0.0002955898],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001090806,"about_ca_system_score_gemma":0.0001176147,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002051846,"about_ca_topic_score_gemma":0.00003492706,"domain_scores_codex":[0.996773,0.00005260763,0.001035285,0.0007799745,0.000667525,0.0006916249],"domain_scores_gemma":[0.9974427,0.0002526542,0.0005313697,0.001299822,0.0001861787,0.0002872601],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006053587,0.0006166459,0.0043318,0.0001612127,0.0008601338,0.00002926442,0.0002258524,0.00002542347,0.9537052,0.00260055,0.00005730488,0.03732609],"study_design_scores_gemma":[0.000979063,0.0001087954,0.005999748,0.00005465686,0.0009672546,0.0001113361,0.001059594,0.0003607791,0.7685771,0.0009570198,0.2195303,0.001294403],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9552085,0.00275648,0.0006515813,0.0001608258,0.000130069,0.000120512,0.0001217341,0.0001873023,0.04066302],"genre_scores_gemma":[0.9842094,0.0008052564,0.001136239,0.00007417125,0.0001600594,0.0000323413,0.0001488161,0.0001298651,0.01330384],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.219473,"threshold_uncertainty_score":0.9996784,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02143482337092898,"score_gpt":0.2315367350463901,"score_spread":0.2101019116754611,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}