{"id":"W1976218748","doi":"10.1021/ic801657g","title":"Reactions of Tertiary Phosphines with Alcohols in Aqueous Media","year":2008,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Organophosphorus compounds synthesis","field":"Chemistry","cited_by":15,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"","keywords":"Chemistry; Aqueous medium; Aqueous solution; Tertiary alcohols; Organic chemistry; Medicinal chemistry; Alcohol","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001096223,0.0005443157,0.0001781208,0.0001215364,0.0001218527,0.000192348,0.0002643812,0.0002067079,0.00200778],"category_scores_gemma":[0.0001677967,0.0001480662,0.0001568387,0.0001369492,0.0001570241,0.0003336676,0.0002623148,0.0003932253,0.0006350562],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002503917,"about_ca_system_score_gemma":0.0001148409,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004171485,"about_ca_topic_score_gemma":0.00065633,"domain_scores_codex":[0.9998758,0.00002102215,0.000008537888,0.00002988588,0.00002958678,0.00003512586],"domain_scores_gemma":[0.9999088,0.00002147308,0.00003437511,0.000008033199,0.00001303477,0.00001433341],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00009365867,0.00001105676,0.0000836707,0.000100426,0.000006663882,0.0000710169,0.00004590428,0.0001606141,0.9968271,0.0001407865,0.0000387792,0.002420363],"study_design_scores_gemma":[0.000003716178,0.00009904127,0.0001401823,0.000002053898,0.000004321701,0.00007410261,0.000008680802,0.0001536782,0.9985644,0.00002214578,0.0009260888,0.00000167246],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9781383,0.003221097,0.009925226,0.00008766,0.00003686499,0.00006119304,0.0002160022,0.0002523853,0.008061322],"genre_scores_gemma":[0.9920186,0.00128299,0.002059977,0.00002579398,0.000009858058,0.00001884042,0.0001890847,0.00003327678,0.00436164],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00200778,"threshold_uncertainty_score":0.006716728,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009369272794926765,"score_gpt":0.1921811002216961,"score_spread":0.1828118274267693,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}