{"id":"W1976346129","doi":"10.1039/c3dt32781g","title":"Understanding the redox properties of dinuclear ruthenium(ii) complexes by a joint experimental and theoretical analysis","year":2013,"lang":"en","type":"article","venue":"Dalton Transactions","topic":"Metal complexes synthesis and properties","field":"Medicine","cited_by":16,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"Université Pierre et Marie Curie; Università degli Studi di Messina; Université de Montréal; Centre National de la Recherche Scientifique; Ministero dell’Istruzione, dell’Università e della Ricerca","keywords":"Chemistry; Redox; Bridging ligand; Ligand (biochemistry); Redistribution (election); Crystallography; Electronic structure; Photochemistry; Computational chemistry; Inorganic chemistry; Crystal structure","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001531211,0.0001323212,0.0003431363,0.0001038787,0.0003739643,0.00004335661,0.00006842519,0.00004461154,0.00217381],"category_scores_gemma":[0.00001325663,0.00007291295,0.0001791548,0.0002113392,0.00073701,0.00009427004,0.00001307647,0.0001356436,0.000007716834],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00003672864,"about_ca_system_score_gemma":0.00001452107,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002148924,"about_ca_topic_score_gemma":0.000007157782,"domain_scores_codex":[0.9990568,0.00009424054,0.0002833685,0.0001814948,0.0002179716,0.0001661317],"domain_scores_gemma":[0.9995436,0.00004696793,0.00005326609,0.0002303047,0.00003936141,0.00008650273],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00009537455,0.0001858023,0.00008716359,0.00004832743,0.0005683929,2.282793e-7,0.003070012,0.00001007354,0.9854617,0.01006618,0.0002477884,0.000158979],"study_design_scores_gemma":[0.0007834125,0.0007274945,0.00173044,0.0001378498,0.001790954,0.00004228534,0.01974908,0.01208781,0.9599898,0.001634366,0.001032948,0.0002934991],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9738712,0.0013547,0.01915243,0.003223823,0.00003735991,0.0004449914,0.0000277931,0.00004358647,0.00184413],"genre_scores_gemma":[0.9991521,0.00005587046,0.0002586487,0.0001292395,0.00001437188,0.00004304557,0.000005096888,0.00001589168,0.0003256955],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02547182,"threshold_uncertainty_score":0.9987383,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.08765451483800399,"score_gpt":0.2559400040276803,"score_spread":0.1682854891896763,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}