{"id":"W1976467817","doi":"10.1128/aem.07694-11","title":"Cloning, Baeyer-Villiger Biooxidations, and Structures of the Camphor Pathway 2-Oxo-Δ <sup>3</sup> -4,5,5-Trimethylcyclopentenylacetyl-Coenzyme A Monooxygenase of Pseudomonas putida ATCC 17453","year":2012,"lang":"en","type":"article","venue":"Applied and Environmental Microbiology","topic":"Microbial Metabolic Engineering and Bioproduction","field":"Biochemistry, Genetics and Molecular Biology","cited_by":55,"is_retracted":false,"has_abstract":true,"ca_institutions":"Centre in Green Chemistry and Catalysis; McGill University; National Research Council Canada; Biotechnology Research Institute","funders":"Argonne National Laboratory; Basic Energy Sciences; National Research Council Canada; Natural Sciences and Engineering Research Council of Canada; Canadian Institutes of Health Research; Eli Lilly and Company; U.S. Department of Energy","keywords":"Pseudomonas putida; Stereochemistry; Monooxygenase; Cofactor; Flavin adenine dinucleotide; Substrate (aquarium); Escherichia coli; Biochemistry; Chemistry; Isomerase; Enzyme; Biology; Cytochrome P450","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00007175468,0.0002757759,0.0001730902,0.0001737079,0.0001542076,0.0003258077,0.0002464355,0.0002502865,0.0002866944],"category_scores_gemma":[0.0001866951,0.0001693605,0.0002110164,0.0002934839,0.0001319204,0.0002062576,0.00009196723,0.0004566194,0.0002152203],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005263574,"about_ca_system_score_gemma":0.0001749054,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.002460358,"about_ca_topic_score_gemma":0.002119571,"domain_scores_codex":[0.9999503,0.000007654138,0.000004405326,0.00001093979,0.00001707225,0.000009709003],"domain_scores_gemma":[0.9999275,0.00001480945,0.00002124735,0.000008059641,0.00001111074,0.00001732775],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001530978,0.00004971623,0.001178527,0.00003271833,0.000007542645,0.000180698,0.0001001119,0.0007743408,0.9936559,0.0002593235,0.00007961422,0.003528402],"study_design_scores_gemma":[0.00006127992,0.000423501,0.04231688,0.00001782832,0.00004394222,0.001141789,0.0004658133,0.007575823,0.9403002,0.0004732224,0.007148724,0.00003096599],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9978936,0.0005557311,0.0009208912,0.00005719773,0.000005004693,0.00000820302,0.0002151279,0.00001254077,0.000331615],"genre_scores_gemma":[0.9896252,0.0009143108,0.005697653,0.00002828034,0.00000755682,0.00002028595,0.002228548,0.00001582239,0.001462329],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002460358,"threshold_uncertainty_score":0.004892051,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.003781979929297505,"score_gpt":0.1741346208344317,"score_spread":0.1703526409051342,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}