{"id":"W1976547638","doi":"10.1063/1.2172238","title":"Hot bands in jet-cooled and ambient temperature spectra of chloromethylene","year":2006,"lang":"en","type":"article","venue":"The Journal of Chemical Physics","topic":"Spectroscopy and Laser Applications","field":"Chemistry","cited_by":21,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Brookhaven National Laboratory; National Research Council Canada; U.S. Department of Energy","keywords":"Excited state; Chemistry; Atomic physics; Ground state; Spectral line; Absorption spectroscopy; Ab initio; Spectroscopy; Ab initio quantum chemistry methods; Rotational temperature; Excimer laser; Molecular physics; Laser; Physics; Molecule; Optics","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001347372,0.0001002325,0.0002242244,0.00001716591,0.00002049397,0.000009856451,0.000187682,0.00006410277,0.00005550889],"category_scores_gemma":[0.00001362965,0.00006679367,0.00006882687,0.0001636554,0.0000986821,0.00005303372,0.00002567439,0.0003870529,7.894894e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00003850658,"about_ca_system_score_gemma":0.00002769731,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002172789,"about_ca_topic_score_gemma":0.000001931579,"domain_scores_codex":[0.9992989,0.00001044374,0.0003099168,0.00007076929,0.0001853668,0.0001245696],"domain_scores_gemma":[0.9994237,0.0001137546,0.0002013423,0.0001667139,0.00005594249,0.00003847898],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001248012,0.0001834549,0.000467281,0.00002700455,0.00001802367,0.000001368472,0.000114833,0.00004433983,0.9980192,0.0005054369,0.0003707909,0.0001234766],"study_design_scores_gemma":[0.000563507,0.00001930739,0.0009445574,0.000046255,0.00004589027,0.00001870096,0.00004850456,0.00006436156,0.9895594,0.008498123,0.000123567,0.00006786658],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9977576,0.0005431487,0.00003949642,0.0002565098,0.00001270246,0.00002546423,0.000007405651,0.000004741208,0.001352898],"genre_scores_gemma":[0.9993418,0.0000833987,0.0001409342,0.00003032455,0.0003526947,0.000001370128,0.000004008431,0.000009800598,0.00003571063],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00845983,"threshold_uncertainty_score":0.2723767,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005320738286679941,"score_gpt":0.2270065641158511,"score_spread":0.2216858258291711,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}