{"id":"W1976587433","doi":"10.1002/pmic.201100425","title":"Information‐dependent <scp>LC</scp>‐<scp>MS</scp>/<scp>MS</scp> acquisition with exclusion lists potentially generated on‐the‐fly: Case study using a whole cell digest of <i><scp>C</scp>lostridium thermocellum</i>","year":2012,"lang":"en","type":"article","venue":"PROTEOMICS","topic":"Mass Spectrometry Techniques and Applications","field":"Chemistry","cited_by":23,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Winnipeg; University of Manitoba; Research Manitoba","funders":"Natural Sciences and Engineering Research Council of Canada; Genome Canada","keywords":"Clostridium thermocellum; Chromatography; Mass spectrometry; Chemistry; Retention time; On the fly; Electrospray ionization; Computer science; Cellulose; Biochemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.001044052,0.0006995448,0.0005413365,0.0004097877,0.0006151554,0.001006364,0.001092385,0.0008097864,0.002038814],"category_scores_gemma":[0.001736438,0.0003829233,0.0003530234,0.0006509471,0.0005857529,0.001018629,0.0008705619,0.0007315257,0.001239726],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0006105531,"about_ca_system_score_gemma":0.001004339,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.003562494,"about_ca_topic_score_gemma":0.005289476,"domain_scores_codex":[0.9994122,0.00008754867,0.0000363836,0.0001354935,0.0002523147,0.00007616057],"domain_scores_gemma":[0.9987593,0.0006064404,0.00009977575,0.0001463987,0.0003083112,0.00007976293],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.001607381,0.0002072778,0.003028756,0.000354006,0.00006723872,0.0009935566,0.000224329,0.005363989,0.9456949,0.0003840801,0.001294369,0.04078022],"study_design_scores_gemma":[0.00004516028,0.0002673547,0.003824218,0.00001109281,0.00003707022,0.0006720435,0.00004779324,0.02930222,0.9621789,0.0002584053,0.003284943,0.00007075675],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8213462,0.0008771432,0.1673243,0.0005618392,0.00003079954,0.0003292523,0.00139365,0.00563929,0.002497574],"genre_scores_gemma":[0.7483772,0.0005316273,0.2433703,0.0005188399,0.00002401662,0.0002835162,0.003129638,0.0009007294,0.002864242],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003562494,"threshold_uncertainty_score":0.007083476,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01481309431282216,"score_gpt":0.2346600229295553,"score_spread":0.2198469286167331,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}