{"id":"W1976931739","doi":"10.1139/v08-122","title":"Unexpectedly different reactions of [(arene)Mn(CO)<sub>3</sub>]<sup>+</sup> cations (arene = trindane, indane, tetralin, or dibenzosuberane) with potassium <i>t</i>-butoxide — C-H insertions, haptotropic shifts, dimerization, or elimination","year":2008,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Lanthanide and Transition Metal Complexes","field":"Materials Science","cited_by":8,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Chemistry; Deprotonation; Medicinal chemistry; Indane; Ligand (biochemistry); Stereochemistry; Tetralin; Denticity; Yield (engineering); Hydride; Alkyl; Crystallography; Crystal structure; Metal; Solvent; Ion","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001725257,0.0004288136,0.0002080338,0.00009111917,0.0001776528,0.0002294671,0.0003558333,0.0003383964,0.001443603],"category_scores_gemma":[0.0002740805,0.0001695227,0.0002456,0.00009532152,0.0002625365,0.0002900184,0.0002864974,0.0004600782,0.0005809396],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002824113,"about_ca_system_score_gemma":0.0001572057,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007752433,"about_ca_topic_score_gemma":0.002203347,"domain_scores_codex":[0.9998108,0.00003258061,0.00001255555,0.00004248206,0.00003594996,0.00006570765],"domain_scores_gemma":[0.9998366,0.000029991,0.0000495619,0.0000335375,0.00001962415,0.00003064243],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001970981,0.0000217413,0.0001788207,0.00005666747,0.00001448414,0.00008923517,0.00004308284,0.0001266623,0.9978477,0.0002016173,0.00007971453,0.00114315],"study_design_scores_gemma":[0.000007533227,0.0001305006,0.0005767862,0.000001880835,0.000008353334,0.0001789565,0.00001751673,0.0002538759,0.9976866,0.00003395668,0.001099178,0.000004950183],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9899582,0.0004310654,0.003686122,0.00006846646,0.00008612018,0.00006214011,0.0001372532,0.000139132,0.005431475],"genre_scores_gemma":[0.9946108,0.0002005183,0.001926711,0.00003648187,0.000006018192,0.00002276581,0.0001491858,0.00002959987,0.003017883],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001443603,"threshold_uncertainty_score":0.004829288,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01952461058431375,"score_gpt":0.2185796215544631,"score_spread":0.1990550109701494,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}