{"id":"W1976931739","doi":"10.1139/v08-122","title":"Unexpectedly different reactions of [(arene)Mn(CO)<sub>3</sub>]<sup>+</sup> cations (arene = trindane, indane, tetralin, or dibenzosuberane) with potassium <i>t</i>-butoxide — C-H insertions, haptotropic shifts, dimerization, or elimination","year":2008,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Lanthanide and Transition Metal Complexes","field":"Materials Science","cited_by":8,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Chemistry; Deprotonation; Medicinal chemistry; Indane; Ligand (biochemistry); Stereochemistry; Tetralin; Denticity; Yield (engineering); Hydride; Alkyl; Crystallography; Crystal structure; Metal; Solvent; Ion","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001514967,0.0003146182,0.0005025037,0.0002877199,0.0005153763,0.00008951651,0.0004449795,0.0001611637,0.0008179498],"category_scores_gemma":[0.0002960593,0.0002345723,0.0001380532,0.0006260975,0.000327239,0.0004727268,0.00001182201,0.0003321701,0.000009953555],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002487937,"about_ca_system_score_gemma":0.002409342,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0009639608,"about_ca_topic_score_gemma":0.005073996,"domain_scores_codex":[0.997637,0.0001071173,0.001016795,0.0003028243,0.0005126298,0.0004235986],"domain_scores_gemma":[0.9973911,0.0001392273,0.0006473482,0.0004039213,0.0007574952,0.0006609327],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002372847,0.0001406826,0.001820411,0.0001415234,0.00007344896,0.0002250099,0.0008225491,0.0009878288,0.9945166,0.0000428248,0.0009098968,0.00008198273],"study_design_scores_gemma":[0.001120822,0.0002008901,0.01881455,0.0002455452,0.0001247047,0.001215342,0.0005055123,0.00004787133,0.9766251,0.0001157685,0.0006683873,0.0003154704],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9967118,0.0001815818,0.001309552,0.0007890158,0.0001311251,0.0001633968,0.0005028446,0.00003181579,0.0001788685],"genre_scores_gemma":[0.998402,0.0001407176,0.0005962628,0.0001149382,0.000200008,0.00001912403,0.0002568545,0.000039919,0.0002301716],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01789142,"threshold_uncertainty_score":0.9565581,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01952461058431375,"score_gpt":0.2185796215544631,"score_spread":0.1990550109701494,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}