{"id":"W1977417967","doi":"10.1016/j.colsurfa.2009.06.027","title":"First experimental evaluation of partial charge transfer during anion adsorption","year":2009,"lang":"en","type":"article","venue":"Colloids and Surfaces A Physicochemical and Engineering Aspects","topic":"Electrochemical Analysis and Applications","field":"Chemistry","cited_by":16,"is_retracted":false,"has_abstract":false,"ca_institutions":"Western University","funders":"","keywords":"Adsorption; Charge transfer coefficient; Partial charge; Halide; Ion; Iodide; Silver iodide; Charge (physics); Chemistry; Electrochemistry; Ab initio; Aqueous solution; Chloride; Bromide; Inorganic chemistry; Electrode; Chemical physics; Analytical Chemistry (journal); Materials science; Physical chemistry; Silver halide; Molecule; Cyclic voltammetry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0005880074,0.0005602788,0.0004958582,0.0001389732,0.0008427476,0.0005837053,0.0007150685,0.0009402847,0.003630689],"category_scores_gemma":[0.001231551,0.0002461162,0.0002654425,0.0002818131,0.0006677487,0.0007072799,0.0005866239,0.0008486956,0.0005675989],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004543651,"about_ca_system_score_gemma":0.0002331556,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0009438656,"about_ca_topic_score_gemma":0.0007669718,"domain_scores_codex":[0.9994895,0.00008534992,0.00001766422,0.00009411333,0.0001594137,0.0001539668],"domain_scores_gemma":[0.9991158,0.0004384617,0.00006556373,0.0001567405,0.0001783936,0.00004506237],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003667432,0.00006927359,0.0002140494,0.0001020205,0.00001075977,0.00006738924,0.000125343,0.00005203793,0.9953598,0.0001214228,0.0001619922,0.003349028],"study_design_scores_gemma":[0.0000122171,0.0003499461,0.000875691,0.000003068232,0.000008119619,0.00005683205,0.00005456235,0.0003383467,0.9974489,0.00003181993,0.0008148757,0.000005589748],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9869148,0.001064244,0.007409325,0.0001341606,0.00009081034,0.0001094184,0.0003274522,0.0001696845,0.003780125],"genre_scores_gemma":[0.994009,0.0004740604,0.00228599,0.00007024869,0.00003278393,0.00005040174,0.0001814238,0.0000411613,0.002854955],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003630689,"threshold_uncertainty_score":0.01214588,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008247395968684857,"score_gpt":0.2182986384590831,"score_spread":0.2100512424903983,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}