{"id":"W1977484200","doi":"10.1139/v08-100","title":"Metal-induced facile synthesis of a tricyclic system — 10-Methyl-12-thia-2,9-diaza-tricyclo[8.3.1.0<sup>3,8</sup>]tetradeca-3,5,7-triene-1-carbonitrile. Formation of an intramolecular carbon–carbon bond","year":2008,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Chemical Reaction Mechanisms","field":"Chemistry","cited_by":2,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Chemistry; Nickel; Intramolecular force; Tricyclic; Cyanide; Metal; Perchlorate; Medicinal chemistry; Carbon fibers; Stereochemistry; Organic chemistry; Ion","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0000685682,0.0002096423,0.0001571555,0.0001616383,0.0001936894,0.0002191121,0.000338144,0.0001632522,0.001913471],"category_scores_gemma":[0.0001584522,0.0001059207,0.000101708,0.0001685634,0.0001476877,0.0001426886,0.0002468061,0.0002836369,0.000587564],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003167596,"about_ca_system_score_gemma":0.0003541378,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005540348,"about_ca_topic_score_gemma":0.002340587,"domain_scores_codex":[0.999912,0.00001059038,0.000006599852,0.00002353233,0.00002151571,0.00002565802],"domain_scores_gemma":[0.9999318,0.000008241902,0.00001902127,0.000009688245,0.00001094598,0.00002019163],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005938251,0.00002499376,0.00009717879,0.00009491116,0.00000904282,0.000111935,0.00004593181,0.0002277393,0.9922495,0.0007735454,0.000187349,0.006118542],"study_design_scores_gemma":[0.00001403157,0.0003481817,0.0007017598,0.000007270542,0.0000114902,0.0002491489,0.00001918088,0.0005123893,0.9908087,0.00006376565,0.007256062,0.000007891127],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9594232,0.002503595,0.008602715,0.00009328518,0.00007127134,0.0001445584,0.0005632071,0.0002523263,0.02834574],"genre_scores_gemma":[0.9869879,0.0007124562,0.006622124,0.00003150682,0.000007395457,0.0000576153,0.0004163418,0.00002736663,0.00513729],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001913471,"threshold_uncertainty_score":0.006401181,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01457404125073509,"score_gpt":0.2030622422645685,"score_spread":0.1884882010138334,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}