{"id":"W1977552244","doi":"10.1021/om049137e","title":"Intermolecular Activation of Hydrocarbon C−H Bonds Initiated by the Tungsten Hydrocarbyl Hydrido Complexes Cp*W(NO)(R)(H)(PMe<sub>3</sub>) (R = Alkyl, Aryl)","year":2005,"lang":"en","type":"article","venue":"Organometallics","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":12,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"","keywords":"Chemistry; Trimethylphosphine; Isomerization; Oxidative addition; Reductive elimination; Aryl; Intramolecular force; Stereochemistry; Benzene; Alkyl; Medicinal chemistry; Cis–trans isomerism; Crystal structure; Crystallography; Catalysis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0003427436,0.0006844355,0.0009165556,0.0002470168,0.0002705783,0.0001430904,0.001175144,0.000296701,0.005700348],"category_scores_gemma":[0.0002596977,0.00058096,0.0004654975,0.001035582,0.0004519738,0.0003902625,0.0004069458,0.0005043907,0.0002819733],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002339441,"about_ca_system_score_gemma":0.00009879027,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00005636536,"about_ca_topic_score_gemma":0.00002189693,"domain_scores_codex":[0.9963828,0.00008186297,0.001150922,0.0008252259,0.0008628877,0.0006962947],"domain_scores_gemma":[0.9971545,0.0002708942,0.000709229,0.001429362,0.0002055035,0.0002304527],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005886368,0.0004150387,0.0001193919,0.00009284237,0.0005936892,0.0000040045,0.0002649186,0.00004479417,0.9792303,0.0002276173,0.0007952426,0.01815324],"study_design_scores_gemma":[0.0006269283,0.0000654427,0.0002981882,0.0000757359,0.0003556724,0.00002492005,0.0001601673,0.002155536,0.9490486,0.0002583451,0.04629464,0.0006358417],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.972649,0.0007582944,0.0002962807,0.0009096035,0.00006121187,0.0002132431,0.0001344949,0.0002105274,0.02476737],"genre_scores_gemma":[0.9968858,0.0002769528,0.0001168498,0.0004097802,0.000305866,0.00005438482,0.0007163523,0.0001703317,0.001063617],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0454994,"threshold_uncertainty_score":0.9996642,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01249385662488755,"score_gpt":0.2115734021243687,"score_spread":0.1990795454994812,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}