{"id":"W1977707488","doi":"10.1021/ic7007478","title":"Interaction of Tertiary Phosphines with Lignin-Type,<i>α</i>,<i>β</i>-Unsaturated Aldehydes in Water","year":2007,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Organophosphorus compounds synthesis","field":"Chemistry","cited_by":21,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"","keywords":"Chemistry; Lignin; Organic chemistry; Medicinal chemistry; Stereochemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001802814,0.0004463969,0.0001542754,0.00009744918,0.0001153378,0.0001867973,0.0002306428,0.0002052982,0.001647748],"category_scores_gemma":[0.0001813003,0.0001839718,0.0001725777,0.00009988953,0.0001922057,0.0003031982,0.0002163173,0.0003302786,0.0004112684],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001470581,"about_ca_system_score_gemma":0.000130699,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005991957,"about_ca_topic_score_gemma":0.0006298675,"domain_scores_codex":[0.9998915,0.00002226889,0.000006040908,0.00002590454,0.00001640333,0.00003777552],"domain_scores_gemma":[0.9999149,0.00003388659,0.00001876963,0.000006842997,0.000008227533,0.00001740108],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001212487,0.00001103524,0.000122062,0.00005455014,0.000006143777,0.00006244632,0.0000431351,0.0001832717,0.9980248,0.00008746483,0.00001769518,0.001266155],"study_design_scores_gemma":[0.00000688109,0.0002246594,0.0002906494,0.000002073217,0.00000450027,0.000034334,0.00001732694,0.0003251742,0.9986406,0.00002034328,0.0004302064,0.000003156244],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9962271,0.0004301417,0.001243673,0.00003080709,0.000008343183,0.00001737723,0.00004202698,0.0000386507,0.001961902],"genre_scores_gemma":[0.9971577,0.0003854585,0.0008389148,0.00002253751,0.000005094145,0.00001060377,0.00005976897,0.00001338865,0.001506585],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001647748,"threshold_uncertainty_score":0.005512238,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005260521959315273,"score_gpt":0.2061336061406001,"score_spread":0.2008730841812849,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}