{"id":"W1977916996","doi":"10.1016/j.molcata.2008.05.009","title":"An evaluation of the Noyori system “in reverse”: Thermodynamic and kinetic parameters of secondary alcohol transfer dehydrogenation catalyzed by [(η6-1-iPr-4-Me-C6H4)Ru(HN-CR′R″-CR′R″NTs)], R′=H, Me; Ph, R″=H, Me","year":2008,"lang":"en","type":"article","venue":"Journal of Molecular Catalysis A Chemical","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":6,"is_retracted":false,"has_abstract":false,"ca_institutions":"University of Guelph","funders":"Ernst Schering Foundation; University of Guelph","keywords":"Dehydrogenation; Chemistry; Ketone; Catalysis; Tosyl; Oxidizing agent; Cyclohexanone; Transfer hydrogenation; Medicinal chemistry; Alkene; Isopropyl alcohol; Solvent; Ruthenium; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002062692,0.0001849485,0.0002718398,0.0001560228,0.0001812022,0.0002242549,0.0002902538,0.000214694,0.001532111],"category_scores_gemma":[0.0004370944,0.0001183924,0.0001140276,0.000138976,0.0002560316,0.0003705561,0.0001515216,0.0003335213,0.0002862189],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000279992,"about_ca_system_score_gemma":0.0002019618,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001732563,"about_ca_topic_score_gemma":0.00188405,"domain_scores_codex":[0.9999175,0.00001250911,0.000004545629,0.000024272,0.0000254007,0.0000157754],"domain_scores_gemma":[0.9998926,0.00003837956,0.00001377301,0.00001491684,0.00002739828,0.00001285197],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0009987488,0.00007811656,0.003283761,0.0001177546,0.0000318811,0.00005931233,0.0001527182,0.004767853,0.9829732,0.001172063,0.0002551813,0.006109452],"study_design_scores_gemma":[0.0000194441,0.0003461235,0.004781623,0.00000490601,0.00002437056,0.00006292683,0.00006751515,0.03426911,0.9587203,0.0001441858,0.001537332,0.00002218816],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9981869,0.0001789521,0.0008009915,0.00001848699,0.000008459208,0.000004064808,0.00008664542,0.00001768174,0.0006977946],"genre_scores_gemma":[0.9992053,0.00005543717,0.0002933208,0.000002891249,0.000001241387,0.000003131341,0.0001211441,0.000004974906,0.0003125136],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001732563,"threshold_uncertainty_score":0.005125403,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01097877998778448,"score_gpt":0.2327330003949991,"score_spread":0.2217542204072146,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}