{"id":"W1978022646","doi":"10.1016/j.molstruc.2012.09.045","title":"New zinc(II), palladium(II) and platinum(II) complexes of dl-piperidine-2-carboxylic acid; X-ray crystal structure of trans-[Zn2(μ-Ca)2(Hpa)2Cl6] and anticancer activity of some complexes","year":2012,"lang":"en","type":"article","venue":"Journal of Molecular Structure","topic":"Metal complexes synthesis and properties","field":"Medicine","cited_by":26,"is_retracted":false,"has_abstract":false,"ca_institutions":"McGill University; Royal Victoria Hospital","funders":"","keywords":"Chemistry; Piperidine; Triclinic crystal system; Denticity; Crystal structure; Molar conductivity; Crystallography; Zinc; Carboxylate; Coordination geometry; Stereochemistry; Medicinal chemistry; Inorganic chemistry; Hydrogen bond; Molecule; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001053977,0.0001962893,0.000278755,0.000188537,0.0001561197,0.00038405,0.0005780306,0.0001996827,0.0009540738],"category_scores_gemma":[0.0002352078,0.0002268153,0.00008446084,0.0001865613,0.0001992304,0.0002041196,0.0002135853,0.0003969727,0.0002125018],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004077132,"about_ca_system_score_gemma":0.0001933119,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001256661,"about_ca_topic_score_gemma":0.001521798,"domain_scores_codex":[0.9999175,0.000009854251,0.00001064912,0.0000181518,0.00003022962,0.00001354347],"domain_scores_gemma":[0.9999412,0.000007175892,0.00001329728,0.000005070851,0.000008655234,0.00002443003],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0006529886,0.00005275845,0.0003491698,0.0002988467,0.0000243246,0.0001493893,0.00007317635,0.0007234059,0.9919947,0.0008457257,0.0003364169,0.004499047],"study_design_scores_gemma":[0.0001441594,0.0003175501,0.0009757847,0.000007193522,0.00003388063,0.0004639968,0.00002518674,0.001200875,0.9862401,0.0001092953,0.01047248,0.000009624245],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.979506,0.008311222,0.005562368,0.000305209,0.00006174786,0.00007270952,0.0005093688,0.0002375354,0.005433879],"genre_scores_gemma":[0.9908489,0.002069103,0.003156477,0.00004352782,0.00001289891,0.00002888703,0.000388842,0.00002257616,0.003428835],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001256661,"threshold_uncertainty_score":0.00319165,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01901697366365496,"score_gpt":0.2543055907868912,"score_spread":0.2352886171232363,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}