{"id":"W1978142403","doi":"10.1021/ja0775725","title":"A Germanium(II)-Centered Dication","year":2007,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"N-Heterocyclic Carbenes in Organic and Inorganic Chemistry","field":"Chemistry","cited_by":166,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"","keywords":"Germanium; Chemistry; Dication; Germanium compounds; Crystallography; Raman spectroscopy; Lone pair; Germane; Crystal structure; X-ray crystallography; Nuclear magnetic resonance spectroscopy; Center (category theory); Diffraction; Stereochemistry; Molecule; Silicon; Organic chemistry; Optics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00027781,0.0001699931,0.0003180927,0.000008110847,0.0001262862,0.00001932455,0.0007698555,0.0001017173,0.0003180882],"category_scores_gemma":[0.00009037443,0.0001202193,0.0006928468,0.000229163,0.0004100476,0.00006968888,0.0003042626,0.0006434581,0.000003725472],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004232923,"about_ca_system_score_gemma":0.00006924283,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000009954917,"about_ca_topic_score_gemma":2.631971e-7,"domain_scores_codex":[0.9984553,0.000007912439,0.0005842077,0.0001662765,0.0004747732,0.0003115471],"domain_scores_gemma":[0.998166,0.000109697,0.001055826,0.0004041145,0.0001088265,0.0001555385],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005003739,0.000114528,0.001494018,0.00002215063,0.0001100111,0.000002255471,0.0003143222,3.176908e-7,0.9857287,0.000008765264,0.009710591,0.002444266],"study_design_scores_gemma":[0.0004602678,0.00001481563,0.000514332,0.00004292781,0.0000680474,0.0002555875,0.0005971508,0.000009970299,0.9815397,0.00006437881,0.01629214,0.000140714],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9950659,0.000135179,0.0002347383,0.0009798219,0.0001605506,0.00001991883,0.000005226359,0.00002540906,0.003373262],"genre_scores_gemma":[0.996874,0.0001028278,0.0006513431,0.0009080449,0.001030655,5.264292e-7,0.000002141145,0.00002669262,0.0004037277],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00658155,"threshold_uncertainty_score":0.4902401,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007863859656802379,"score_gpt":0.249888771222149,"score_spread":0.2420249115653466,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}