{"id":"W1978142403","doi":"10.1021/ja0775725","title":"A Germanium(II)-Centered Dication","year":2007,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"N-Heterocyclic Carbenes in Organic and Inorganic Chemistry","field":"Chemistry","cited_by":166,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"","keywords":"Germanium; Chemistry; Dication; Germanium compounds; Crystallography; Raman spectroscopy; Lone pair; Germane; Crystal structure; X-ray crystallography; Nuclear magnetic resonance spectroscopy; Center (category theory); Diffraction; Stereochemistry; Molecule; Silicon; Organic chemistry; Optics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001090128,0.0002865531,0.0004757328,0.0001200102,0.0003512708,0.0005156875,0.0005510006,0.0003315049,0.002816365],"category_scores_gemma":[0.0002096361,0.000169709,0.00009058481,0.0001411567,0.0002697357,0.0002419586,0.0005469934,0.0003251325,0.0005723138],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000437433,"about_ca_system_score_gemma":0.0002290782,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005144567,"about_ca_topic_score_gemma":0.0008138671,"domain_scores_codex":[0.999806,0.00002525182,0.00001392978,0.00006299553,0.00005054703,0.00004127748],"domain_scores_gemma":[0.9999276,0.000006569806,0.00001250971,0.00001501115,0.00001104145,0.00002718889],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000495653,0.00004421129,0.0003824879,0.0003761115,0.00004671251,0.0003979303,0.0001433106,0.0004950028,0.9829205,0.00281609,0.003097448,0.008784601],"study_design_scores_gemma":[0.0001793634,0.00114626,0.001207101,0.00001960477,0.00004859265,0.001073602,0.00007290135,0.0009057185,0.957661,0.00050682,0.03713392,0.000045063],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9825549,0.001352002,0.003165497,0.0003704505,0.0001765287,0.00005887779,0.000403027,0.0002021747,0.01171675],"genre_scores_gemma":[0.9902559,0.0003760137,0.003166858,0.0001370566,0.00001435293,0.00002310644,0.0003958153,0.00003981021,0.005591065],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002816365,"threshold_uncertainty_score":0.009421706,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007863859656802379,"score_gpt":0.249888771222149,"score_spread":0.2420249115653466,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}