{"id":"W1978356202","doi":"10.1007/s00216-014-8323-5","title":"An enzyme-linked immuno-mass spectrometric assay with the substrate adenosine monophosphate","year":2014,"lang":"en","type":"article","venue":"Analytical and Bioanalytical Chemistry","topic":"Advanced Proteomics Techniques and Applications","field":"Chemistry","cited_by":15,"is_retracted":false,"has_abstract":false,"ca_institutions":"University of Toronto; Mount Sinai Hospital; University Health Network; Toronto Metropolitan University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Substrate (aquarium); Chemistry; Enzyme; Adenosine; Adenosine monophosphate; Chromatography; Biochemistry; Biology","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.002450066,0.002940685,0.001617862,0.002375433,0.0009499622,0.001126892,0.003177609,0.002660007,0.002407485],"category_scores_gemma":[0.001774601,0.00130727,0.001211594,0.001451843,0.001148374,0.001032494,0.001113262,0.003422307,0.005088769],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.001013265,"about_ca_system_score_gemma":0.001410048,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005008832,"about_ca_topic_score_gemma":0.001383884,"domain_scores_codex":[0.9958027,0.001071922,0.0002298526,0.001016133,0.001559035,0.0003204548],"domain_scores_gemma":[0.9978918,0.0006010752,0.000233394,0.0003085841,0.0006299469,0.0003350614],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002018427,0.0001809314,0.0003661811,0.0001525357,0.00004915741,0.00004550108,0.00002319953,0.00006932663,0.9936419,0.0002501667,0.0002987201,0.004720601],"study_design_scores_gemma":[0.00008685108,0.0007046369,0.002400791,0.0000341724,0.00009345321,0.0008082223,0.00002163474,0.003814337,0.9883929,0.0003554446,0.003246208,0.00004142388],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"methods","genre_gemma":"methods","genre_scores_codex":[0.1772558,0.007381554,0.7937933,0.001023285,0.001884162,0.002346755,0.001887779,0.00432133,0.0101061],"genre_scores_gemma":[0.2502166,0.004092382,0.7174429,0.002060882,0.0006731994,0.003703812,0.005280413,0.000290147,0.01623969],"genre_candidate":"methods","genre_consensus":"methods","teacher_disagreement_score":0.003177609,"threshold_uncertainty_score":0.01295733,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007987137609795013,"score_gpt":0.2411835053914056,"score_spread":0.2331963677816106,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}