{"id":"W1978361525","doi":"10.1063/1.2131051","title":"Effects of dielectric saturation and ionic screening on the proton self-diffusion coefficients in perfluorosulfonic acid membranes","year":2005,"lang":"en","type":"article","venue":"The Journal of Chemical Physics","topic":"Fuel Cells and Related Materials","field":"Engineering","cited_by":47,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Calgary","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Hydronium; Nafion; Proton; Chemistry; Membrane; Ionic bonding; Dielectric; Sulfonate; Hydrogen bond; Diffusion; Ion; Sulfonic acid; Proton transport; Analytical Chemistry (journal); Physical chemistry; Chemical physics; Thermodynamics; Materials science; Molecule; Polymer chemistry; Electrochemistry; Organic chemistry; Physics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003262376,0.0004173605,0.000381459,0.0003452522,0.0003608002,0.0004194354,0.0003748035,0.0003844555,0.0005237205],"category_scores_gemma":[0.001527353,0.0002669755,0.0003620424,0.00029784,0.0007306022,0.0006936501,0.000517217,0.0004019967,0.00008229437],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0007043741,"about_ca_system_score_gemma":0.0005100999,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.003450725,"about_ca_topic_score_gemma":0.001857644,"domain_scores_codex":[0.9999045,0.00001705978,0.00000499537,0.000008830906,0.00003306599,0.00003158361],"domain_scores_gemma":[0.9993891,0.0003905332,0.0000793582,0.00002967017,0.00008026104,0.00003113841],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"simulation_or_modeling","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003322973,0.0001255468,0.003094141,0.0001501599,0.00003225908,0.0006263727,0.0001972996,0.7781253,0.2017394,0.008514835,0.0001222385,0.006940161],"study_design_scores_gemma":[0.00002840394,0.0001120801,0.0007410194,0.000008455225,0.00001237049,0.00005853388,0.00003508319,0.9300666,0.06777804,0.0009855523,0.0001588297,0.00001504225],"study_design_candidate":"bench_or_experimental","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9927394,0.0001446169,0.005521346,0.00007613614,0.000004684252,0.000009115236,0.00001936444,0.00002723511,0.001457944],"genre_scores_gemma":[0.9983626,0.0001748065,0.001049704,0.00001096342,0.000003073419,0.00001067834,0.0000163789,0.00001068917,0.0003610948],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003450725,"threshold_uncertainty_score":0.006861269,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.003898457095073929,"score_gpt":0.1831604097249656,"score_spread":0.1792619526298916,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}