{"id":"W1978521232","doi":"10.1021/jo016019h","title":"Mechanism of Migration of the Trimethylsilyl Group during Reactions of Methoxy[(trimethylsilyl)ethoxy]carbene with <i>N</i>-Phenylmaleimide and C<sub>60</sub>","year":2001,"lang":"en","type":"article","venue":"The Journal of Organic Chemistry","topic":"Synthesis and characterization of novel inorganic/organometallic compounds","field":"Chemistry","cited_by":7,"is_retracted":false,"has_abstract":true,"ca_institutions":"McMaster University","funders":"","keywords":"Chemistry; Trimethylsilyl; Carbene; Alkoxy group; Medicinal chemistry; Carbocation; Oxygen; Group (periodic table); Stereochemistry; Deuterium; Organic chemistry; Alkyl; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001931767,0.000440822,0.0002134174,0.0001828144,0.000221784,0.0002609735,0.0004625447,0.0005252082,0.001152322],"category_scores_gemma":[0.0002108312,0.0002656208,0.0002512457,0.00009443731,0.0004592556,0.0004648254,0.0002181888,0.0004176324,0.0003731215],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000308019,"about_ca_system_score_gemma":0.0001795436,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000516435,"about_ca_topic_score_gemma":0.0006896651,"domain_scores_codex":[0.999897,0.00001231897,0.000004695962,0.00002965379,0.00002885165,0.00002748738],"domain_scores_gemma":[0.9998653,0.00003320261,0.00005112688,0.00001747696,0.00001588242,0.00001704214],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000888226,0.000009791563,0.0002089367,0.00003443808,0.000005346342,0.0001464028,0.0000504094,0.00005800172,0.9977742,0.0001387837,0.00002361951,0.001461157],"study_design_scores_gemma":[0.000005629267,0.0000585563,0.0006654836,0.000001610376,0.000005521008,0.0001719505,0.00001491306,0.0001595046,0.9984256,0.00003028033,0.0004580933,0.000003020146],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9896492,0.001572368,0.006548743,0.0001049144,0.0000319175,0.00004171307,0.000114185,0.0001110721,0.001825907],"genre_scores_gemma":[0.9923087,0.0009728145,0.004182298,0.00005602102,0.000009916052,0.00002934075,0.000142143,0.00002406462,0.002274701],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001152322,"threshold_uncertainty_score":0.00385493,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009397103474082841,"score_gpt":0.1994435021691144,"score_spread":0.1900463986950315,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}