{"id":"W1978767424","doi":"10.1023/b:jtan.0000042168.76400.39","title":"Preparation, characterization and thermal behaviour of samarium(III) cyclotriphosphate(V), SmP3O9·5H2O","year":2004,"lang":"en","type":"article","venue":"Journal of Thermal Analysis and Calorimetry","topic":"Chemical Synthesis and Characterization","field":"Environmental Science","cited_by":2,"is_retracted":false,"has_abstract":false,"ca_institutions":"Institut National de la Recherche Scientifique","funders":"","keywords":"Samarium; Thermogravimetric analysis; Infrared spectroscopy; Powder diffraction; Amorphous solid; Differential thermal analysis; Thermal analysis; Dehydration; Polyphosphate; Thermogravimetry; Analytical Chemistry (journal); Differential scanning calorimetry; Characterization (materials science); Atmospheric temperature range; X-ray crystallography; Crystallography; Materials science; Diffraction; Nuclear chemistry; Infrared; Chemistry; Thermal; Inorganic chemistry; Organic chemistry; Physics; Nanotechnology; Phosphate","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002794357,0.0001229375,0.0003457432,0.00009412328,0.00006863353,0.00004015661,0.0001106741,0.00008185643,0.0005052742],"category_scores_gemma":[0.000024519,0.00009213882,0.0001558877,0.0004346636,0.00009541271,0.0003515696,0.00006268446,0.00009792222,0.000002488123],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00005115063,"about_ca_system_score_gemma":0.00001043442,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000188814,"about_ca_topic_score_gemma":0.000009552703,"domain_scores_codex":[0.9988656,0.00003748904,0.0005186856,0.000155052,0.0003020721,0.0001211153],"domain_scores_gemma":[0.9991496,0.00002549191,0.0005646428,0.0001090056,0.00004022773,0.0001109872],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"observational","study_design_scores_codex":[0.0000954408,0.0001182818,0.2787696,0.000005000577,0.0001592825,0.000002429048,0.0002210215,0.0003165911,0.7125884,0.00001885675,0.000002756822,0.007702406],"study_design_scores_gemma":[0.0003589627,0.00008263811,0.8307932,0.00001184357,0.0005447417,0.000006900186,0.00003160288,0.000187843,0.1677684,0.00002801307,0.00008895309,0.00009691487],"study_design_candidate":"observational","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9968039,0.0001125099,0.002732772,0.000130808,0.0000444446,0.00005043545,0.000008076373,0.000004284444,0.0001127817],"genre_scores_gemma":[0.9993328,0.0001555198,0.0002792474,0.00006746115,0.00007384373,9.628716e-7,0.00001579794,0.000007694133,0.00006661488],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.5520236,"threshold_uncertainty_score":0.5532399,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.004230938401614345,"score_gpt":0.2125680834674094,"score_spread":0.208337145065795,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}