{"id":"W1978839272","doi":"10.1016/j.poly.2013.11.022","title":"Chemistry of gold(III) with pyridine-carboxamide ligands","year":2013,"lang":"en","type":"article","venue":"Polyhedron","topic":"Catalytic Alkyne Reactions","field":"Chemistry","cited_by":11,"is_retracted":false,"has_abstract":false,"ca_institutions":"Western University","funders":"","keywords":"Chemistry; Pyridine; Cyanation; Carboxamide; Ligand (biochemistry); Denticity; Methanol; Catalysis; Medicinal chemistry; Stereochemistry; Oxidative addition; Crystal structure; Crystallography; Organic chemistry; Receptor","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00003798167,0.0001838694,0.0002384178,0.00002021498,0.00003144049,0.00002428272,0.0002112856,0.0001168161,0.002595117],"category_scores_gemma":[0.00003236228,0.0001608487,0.00007948414,0.0001383516,0.000121051,0.0001369915,0.00006156418,0.0001918639,0.0001279209],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0000929911,"about_ca_system_score_gemma":0.00008302822,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00115325,"about_ca_topic_score_gemma":0.00001718925,"domain_scores_codex":[0.9989735,0.000001522814,0.0002491524,0.0002538254,0.0002417474,0.0002802522],"domain_scores_gemma":[0.9990088,0.00005926694,0.0001495406,0.0005722021,0.00008012837,0.0001300546],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001974925,0.00008905301,0.00279693,0.0001448016,0.00007603172,0.000003748632,0.0001061968,0.00001574849,0.993342,0.00004897887,0.001760104,0.001596662],"study_design_scores_gemma":[0.0005966043,0.00001337022,0.0009827492,0.00007511651,0.00005555881,0.000057873,0.0002511319,0.0003835022,0.9952884,0.00007830947,0.002008158,0.0002091695],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8717229,0.000139935,0.00001956749,0.0002166357,0.00002731479,0.00005519281,0.00001231142,0.0001023435,0.1277037],"genre_scores_gemma":[0.9828869,0.00001870149,0.00007121212,0.00001785936,0.0001723765,0.00004387007,0.00003816665,0.00003812178,0.01671284],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1111639,"threshold_uncertainty_score":0.9983166,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006020352005993049,"score_gpt":0.1993032003418278,"score_spread":0.1932828483358348,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}