{"id":"W1978917147","doi":"10.1021/jo060841+","title":"Diboron and Triboron Compounds Based on Linear and Star-Shaped Conjugated Ligands with 8-Hydroxyquinolate Functionality:  Impact of Intermolecular Interaction and Boron Coordination on Luminescence","year":2006,"lang":"en","type":"article","venue":"The Journal of Organic Chemistry","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":81,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; HOMO/LUMO; Conjugated system; Intermolecular force; Ligand (biochemistry); Chromophore; Quinoline; Molecule; Photochemistry; Chelation; Crystallography; Organic chemistry; Polymer","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001082347,0.000236887,0.0001558792,0.0001229854,0.00008887288,0.0002376425,0.000278422,0.0002254189,0.001257922],"category_scores_gemma":[0.000102135,0.0001036883,0.00007548178,0.0001504522,0.0001642462,0.0002701328,0.0001809004,0.0001507846,0.0003496305],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002413504,"about_ca_system_score_gemma":0.0001091727,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006357439,"about_ca_topic_score_gemma":0.001309767,"domain_scores_codex":[0.9999337,0.0000140561,0.000004288372,0.00001537778,0.00001088953,0.00002171875],"domain_scores_gemma":[0.9999322,0.00001223208,0.00001882034,0.000003746555,0.00000779419,0.00002523486],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001759851,0.00002323727,0.0001349356,0.0001081241,0.00000611803,0.00003573644,0.00002325228,0.0001721493,0.9969189,0.000243609,0.00004050037,0.002117475],"study_design_scores_gemma":[0.0000352127,0.0006288849,0.0008656835,0.000009875423,0.00001541156,0.00008902574,0.00002987622,0.001059284,0.9945388,0.00003573026,0.002679251,0.00001300328],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.996083,0.001110379,0.001072611,0.00003469395,0.000008638809,0.00001715843,0.00008449132,0.00004902477,0.001539832],"genre_scores_gemma":[0.9951493,0.000592505,0.002409298,0.00004885659,0.000002453258,0.00001976713,0.00009636029,0.00001433026,0.001667126],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001257922,"threshold_uncertainty_score":0.004208207,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006392309845737334,"score_gpt":0.2297029448967944,"score_spread":0.2233106350510571,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}