{"id":"W1978973562","doi":"10.1002/adsc.200800232","title":"Copper‐Catalyzed Four‐Component Coupling between Aldehydes, Amines, Alkynes, and Carbon Dioxide","year":2008,"lang":"en","type":"article","venue":"Advanced Synthesis & Catalysis","topic":"Carbon dioxide utilization in catalysis","field":"Chemical Engineering","cited_by":131,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University","funders":"Natural Sciences and Engineering Research Council of Canada; Canada Research Chairs","keywords":"Chemistry; Copper; Carbon dioxide; Catalysis; Component (thermodynamics); Coupling (piping); Organic chemistry; Metallurgy","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0003143477,0.000721472,0.001363393,0.0005279503,0.0002859681,0.00003920922,0.0005764603,0.0002810142,0.00006637804],"category_scores_gemma":[0.001235449,0.0007733935,0.0004179282,0.00124934,0.0003076894,0.0004669289,0.0003153479,0.0003612306,0.00004659187],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003626292,"about_ca_system_score_gemma":0.00004681836,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006993546,"about_ca_topic_score_gemma":0.00007948065,"domain_scores_codex":[0.9959689,0.00004974155,0.001109335,0.001218622,0.0008234064,0.0008299711],"domain_scores_gemma":[0.9960768,0.001496795,0.0003722273,0.001395194,0.000195151,0.0004638612],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007077922,0.0001352479,0.0484967,0.0001922942,0.001301762,0.0001368834,0.0004418147,0.0194741,0.9206727,0.0001139606,0.00005448639,0.00890932],"study_design_scores_gemma":[0.001088226,0.00001910984,0.00897848,0.0002034976,0.001471718,0.0001247216,0.0002951113,0.02816678,0.9552849,0.00003955316,0.002757691,0.001570199],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9931833,0.002481632,0.002363761,0.0002070046,0.0001242452,0.0003160223,0.00009515258,0.0006375848,0.000591364],"genre_scores_gemma":[0.9952297,0.001076013,0.002322976,0.00003698366,0.0002281102,0.0002373896,0.0003846289,0.0001809926,0.0003031603],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.03951822,"threshold_uncertainty_score":0.9994717,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01930905649467863,"score_gpt":0.2308450855784118,"score_spread":0.2115360290837332,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}