{"id":"W1978992591","doi":"10.1021/ma0600254","title":"Temperature-Dependent Properties of Telechelic Hydrophobically Modified Poly(<i>N</i>-isopropylacrylamides) in Water:  Evidence from Light Scattering and Fluorescence Spectroscopy for the Formation of Stable Mesoglobules at Elevated Temperatures","year":2006,"lang":"en","type":"article","venue":"Macromolecules","topic":"Hydrogels: synthesis, properties, applications","field":"Biochemistry, Genetics and Molecular Biology","cited_by":131,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"","keywords":"Micelle; Molar mass; Dynamic light scattering; Dispersity; Hydrodynamic radius; Aqueous solution; Polymer; Polymer chemistry; Fluorescence spectroscopy; Cloud point; Chemistry; Static light scattering; Fluorescence; Poly(N-isopropylacrylamide); Copolymer; Materials science; Physical chemistry; Organic chemistry; Nanoparticle; Nanotechnology","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001199684,0.0003029809,0.0001619948,0.0001258358,0.00009382371,0.0001930992,0.0001356022,0.0002179366,0.0004650135],"category_scores_gemma":[0.0002933082,0.000160967,0.0001181745,0.0001253596,0.0002455481,0.0003288143,0.0001106805,0.0003848825,0.0001729943],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001607217,"about_ca_system_score_gemma":0.0001078381,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005721606,"about_ca_topic_score_gemma":0.0003998673,"domain_scores_codex":[0.9999231,0.00001175104,0.000004553699,0.00002066772,0.00002395146,0.00001597061],"domain_scores_gemma":[0.9998306,0.00004672585,0.00006111299,0.000006344671,0.00002711859,0.00002802405],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000320019,0.000003999022,0.0001555059,0.00001074217,0.000001893734,0.00001070486,0.00001551138,0.00005571865,0.9994394,0.000009276325,0.000004200294,0.0002608667],"study_design_scores_gemma":[0.000007074677,0.0001662456,0.004133348,0.000003563069,0.000009438171,0.00005418271,0.00002056677,0.001427838,0.9939616,0.00002174048,0.0001885653,0.000005611163],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9978629,0.0003570911,0.001281564,0.00002009334,0.000003938288,0.000009356917,0.00009590569,0.00002486517,0.0003442424],"genre_scores_gemma":[0.9978576,0.0003036887,0.001186107,0.00002788297,0.000005573319,0.00001986164,0.000155634,0.0000130457,0.0004304588],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0005721606,"threshold_uncertainty_score":0.001555622,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01143931665430113,"score_gpt":0.2165346246416301,"score_spread":0.205095307987329,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}