{"id":"W1978992591","doi":"10.1021/ma0600254","title":"Temperature-Dependent Properties of Telechelic Hydrophobically Modified Poly(<i>N</i>-isopropylacrylamides) in Water:  Evidence from Light Scattering and Fluorescence Spectroscopy for the Formation of Stable Mesoglobules at Elevated Temperatures","year":2006,"lang":"en","type":"article","venue":"Macromolecules","topic":"Hydrogels: synthesis, properties, applications","field":"Biochemistry, Genetics and Molecular Biology","cited_by":131,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"","keywords":"Micelle; Molar mass; Dynamic light scattering; Dispersity; Hydrodynamic radius; Aqueous solution; Polymer; Polymer chemistry; Fluorescence spectroscopy; Cloud point; Chemistry; Static light scattering; Fluorescence; Poly(N-isopropylacrylamide); Copolymer; Materials science; Physical chemistry; Organic chemistry; Nanoparticle; Nanotechnology","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002898117,0.0002568405,0.0002999943,0.00007156362,0.0001621988,0.00006191599,0.0003824862,0.0001530825,0.000004478879],"category_scores_gemma":[0.00008790872,0.0001644486,0.00007983006,0.0001107268,0.0002213035,0.00002661502,0.0002203075,0.0001057667,0.00000178522],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00005135191,"about_ca_system_score_gemma":0.00005053123,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001244926,"about_ca_topic_score_gemma":0.0005378562,"domain_scores_codex":[0.9983233,0.00009557766,0.0005601611,0.0004490681,0.0002258255,0.0003461092],"domain_scores_gemma":[0.9991133,0.00003535328,0.0001634843,0.0005094196,0.000139247,0.00003914928],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003765786,0.00007406821,0.0004916493,0.0001502622,0.00003176353,0.000001166715,0.0001875837,0.0002289929,0.9982463,0.00002213828,0.00004431455,0.0001451714],"study_design_scores_gemma":[0.0003780305,0.0001165378,0.0006485789,0.0002176125,0.00003707114,0.00001143477,0.00006726834,0.001120344,0.996963,0.0001219728,0.0001055603,0.0002126268],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9867993,0.01094839,0.0007504929,0.000546099,0.00002610873,0.000833162,0.00006274661,0.00001855796,0.00001512224],"genre_scores_gemma":[0.9971853,0.0006918437,0.001563881,0.00004636851,0.00005402529,0.0002812353,0.00006948184,0.00003711376,0.00007074304],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01038599,"threshold_uncertainty_score":0.6706019,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01143931665430113,"score_gpt":0.2165346246416301,"score_spread":0.205095307987329,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}