{"id":"W1979119485","doi":"10.1002/cctc.201402201","title":"Catalytic Oxidative Carbonylation over Cu<sub>2</sub>O Nanoclusters Supported on Carbon Materials: The Role of the Carbon Support","year":2014,"lang":"en","type":"article","venue":"ChemCatChem","topic":"Carbon dioxide utilization in catalysis","field":"Chemical Engineering","cited_by":53,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Project 211; National Natural Science Foundation of China; Ontario Council on Graduate Studies, Council of Ontario Universities","keywords":"Catalysis; Dimethyl carbonate; Carbonylation; Nanoclusters; Chemistry; Methanol; Formate; Inorganic chemistry; Carbon fibers; Carbon monoxide; Methyl formate; Activated carbon; Oxygen; Organic chemistry; Materials science; Adsorption","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001519464,0.0005458801,0.0003004009,0.0002419577,0.0001659453,0.0002808842,0.0003595443,0.0004492516,0.0005220862],"category_scores_gemma":[0.0003442147,0.0001690445,0.000177144,0.0001964612,0.0002576637,0.0002529175,0.0002119884,0.0002340639,0.0001626254],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003541025,"about_ca_system_score_gemma":0.0002100434,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001482695,"about_ca_topic_score_gemma":0.003874064,"domain_scores_codex":[0.9998298,0.00001457509,0.00001205058,0.00003751539,0.00005527779,0.00005077231],"domain_scores_gemma":[0.9998147,0.00003783103,0.0000486293,0.00001601176,0.00004874905,0.00003407334],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001045442,0.00001779039,0.0001465088,0.00005202603,0.000007846766,0.0000418338,0.000009619884,0.000114651,0.9981928,0.0000400006,0.00003484468,0.001237478],"study_design_scores_gemma":[0.000005256642,0.00006591059,0.000527018,0.000001743888,0.000006753507,0.00002071365,0.000006787923,0.000563251,0.9985746,0.000007150738,0.0002182791,0.000002544175],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9972064,0.0006779537,0.0009265569,0.0000346799,0.0000256176,0.00002140376,0.00007919833,0.0000406682,0.0009875195],"genre_scores_gemma":[0.9979133,0.0002675101,0.001276247,0.00001299254,0.000005498282,0.00001112121,0.00007951748,0.00001054048,0.0004232853],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001482695,"threshold_uncertainty_score":0.002948046,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005983076897849581,"score_gpt":0.2025643582479914,"score_spread":0.1965812813501418,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}