{"id":"W1979223293","doi":"10.1021/om010200z","title":"Structure and Reactivity of the Cationic Nickel Compound [(η<sup>3</sup>:η<sup>1</sup>-Ind(CH<sub>2</sub>)<sub>2</sub>NMe<sub>2</sub>)Ni(PPh<sub>3</sub>)][BPh<sub>4</sub>]","year":2001,"lang":"en","type":"article","venue":"Organometallics","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":56,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"","keywords":"Chemistry; Cationic polymerization; Nickel; Pyridine; Medicinal chemistry; Amine gas treating; Chelation; Hydroamination; Picoline; Reactivity (psychology); Norbornene; Ligand (biochemistry); Phosphine; Stereochemistry; Catalysis; Polymer chemistry; Polymerization; Inorganic chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","sts","scholarly_communication","research_integrity","insufficient_payload"],"consensus_categories":["metaepi_narrow","research_integrity","insufficient_payload"],"category_scores_codex":[0.00211611,0.004224377,0.004928089,0.001487849,0.002521006,0.001296209,0.004358166,0.002676981,0.001592527],"category_scores_gemma":[0.001520383,0.004055043,0.002610303,0.006035832,0.00256836,0.00211554,0.002768837,0.004004048,0.0008326058],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.002009276,"about_ca_system_score_gemma":0.001604246,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001725495,"about_ca_topic_score_gemma":0.0009828062,"domain_scores_codex":[0.9807897,0.00107351,0.004616636,0.005157325,0.004161957,0.004200903],"domain_scores_gemma":[0.9840941,0.001777058,0.003417214,0.007387665,0.00137486,0.001949052],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003822798,0.002168173,0.003508976,0.0009226955,0.002586102,0.0001509479,0.001519343,0.001003423,0.9402801,0.0003868778,0.002407908,0.04468314],"study_design_scores_gemma":[0.003667838,0.0002712506,0.008589111,0.0004536893,0.003051719,0.0009229363,0.001338737,0.002303149,0.9627008,0.001860434,0.01057939,0.004260973],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9854631,0.002215505,0.0002907382,0.001192367,0.0006060097,0.001955448,0.006152393,0.0008031773,0.001321221],"genre_scores_gemma":[0.9855528,0.005707132,0.0001596174,0.0006136877,0.001648881,0.0003245913,0.004751721,0.00102335,0.0002182018],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.04042217,"threshold_uncertainty_score":0.9999453,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01108145739091201,"score_gpt":0.2059421250701062,"score_spread":0.1948606676791942,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}