{"id":"W1979223293","doi":"10.1021/om010200z","title":"Structure and Reactivity of the Cationic Nickel Compound [(η<sup>3</sup>:η<sup>1</sup>-Ind(CH<sub>2</sub>)<sub>2</sub>NMe<sub>2</sub>)Ni(PPh<sub>3</sub>)][BPh<sub>4</sub>]","year":2001,"lang":"en","type":"article","venue":"Organometallics","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":56,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"","keywords":"Chemistry; Cationic polymerization; Nickel; Pyridine; Medicinal chemistry; Amine gas treating; Chelation; Hydroamination; Picoline; Reactivity (psychology); Norbornene; Ligand (biochemistry); Phosphine; Stereochemistry; Catalysis; Polymer chemistry; Polymerization; Inorganic chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00006642337,0.0001395253,0.0001099086,0.00009801515,0.0001752721,0.0003225967,0.0002895736,0.0003377837,0.0017851],"category_scores_gemma":[0.0001767381,0.000132144,0.0000724771,0.0001104515,0.0003087593,0.0001745091,0.0001038711,0.0003080187,0.0002630331],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004191412,"about_ca_system_score_gemma":0.0002395199,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.002080516,"about_ca_topic_score_gemma":0.00186068,"domain_scores_codex":[0.9999367,0.000005305644,0.000002235056,0.00001626453,0.00002167693,0.00001778749],"domain_scores_gemma":[0.9999422,0.00001126362,0.00001430901,0.00000637965,0.00001129053,0.00001449678],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001115221,0.0000167276,0.0001747833,0.00002607086,0.000003506349,0.00004805506,0.00003472259,0.0002482164,0.9982857,0.0002950857,0.00004298555,0.0007126051],"study_design_scores_gemma":[0.00001184883,0.0001733238,0.001978735,0.000002220536,0.000005423149,0.00007806591,0.00002243834,0.001089338,0.9955878,0.0000687766,0.0009746055,0.000007371179],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9974752,0.0001585383,0.0004339194,0.00002445588,0.000004372905,0.00000624621,0.0001096995,0.00003279945,0.00175473],"genre_scores_gemma":[0.9979444,0.00007145922,0.0004257041,0.00001173554,0.000001566626,0.000004979145,0.0001810395,0.0000121909,0.001346968],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002080516,"threshold_uncertainty_score":0.00597173,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01108145739091201,"score_gpt":0.2059421250701062,"score_spread":0.1948606676791942,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}