{"id":"W1979333464","doi":"10.1139/cjc-79-5-6-896","title":"Dithiophosphinates of gold (I); oxidative addition of Cl&lt;sub&gt;2&lt;/sub&gt; to a neutral, dinuclear gold(I) dithiophosphinate complex, and X-ray crystal structures of [AuS&lt;sub&gt;2&lt;/sub&gt;P(C&lt;sub&gt;2&lt;/sub&gt;H&lt;sub&gt;5&lt;/sub&gt;)&lt;sub&gt;2&lt;/sub&gt;]&lt;sub&gt;2&lt;/sub&gt;, [AuS&lt;sub&gt;2&lt;/sub&gt;PPh&lt;sub&gt;2&lt;/sub&gt;]&lt;sub&gt;2&lt;/sub&gt;, Au&lt;sub&gt;2&lt;/sub&gt;(CH&lt;sub&gt;2&lt;/sub&gt;)&lt;sub&gt;2&lt;/sub&gt;PMe&lt;sub&gt;2&lt;/sub&gt;(S&lt;sub&gt;2&lt;/sub&gt;PPh&lt;sub&gt;2&lt;/sub&gt;), and Au&lt;sub&gt;2&lt;/sub&gt;Cl&lt;sub&gt;2&lt;/sub&gt;[(CH&lt;sub&gt;2&lt;/sub&gt;)&lt;sub&gt;2&lt;/sub&gt;PMe&lt;sub&gt;2&lt;/sub&gt;][S&lt;sub&gt;2&lt;/sub&gt;PPh&lt;sub&gt;2&lt;/sub&gt;]","year":2001,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Organometallic Compounds Synthesis and Characterization","field":"Chemistry","cited_by":11,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Chemistry; Crystallography; Moiety; Oxidative addition; Ligand (biochemistry); Ylide; Crystal structure; Intermolecular force; Stereochemistry; Oxidation state; Molecule; Metal; Organic chemistry; Catalysis","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001230525,0.0004424567,0.0002323056,0.0001477339,0.0002717768,0.0001447761,0.000776472,0.0003105551,0.003814084],"category_scores_gemma":[0.0002154028,0.0002336042,0.0001488348,0.0003207258,0.0002794717,0.0001880531,0.0002998469,0.0006989641,0.0006638621],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0007406404,"about_ca_system_score_gemma":0.0007513787,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.01240579,"about_ca_topic_score_gemma":0.0138042,"domain_scores_codex":[0.9998653,0.00001022904,0.000007161824,0.000046758,0.00003204428,0.00003850176],"domain_scores_gemma":[0.9999369,0.00000938327,0.00001320475,0.00001456945,0.00001190623,0.00001392182],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.001495751,0.0000634712,0.0004183806,0.0004640082,0.00004852195,0.0002756622,0.0002264832,0.001398749,0.986813,0.001646137,0.0017243,0.005425577],"study_design_scores_gemma":[0.00005997457,0.0003399842,0.001065286,0.00001644422,0.00002347896,0.0001327725,0.0001188054,0.001094416,0.9902018,0.0001685043,0.006763551,0.00001508941],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9700733,0.0009956538,0.007079816,0.0003529251,0.00008548546,0.0001438543,0.001410862,0.0005206952,0.01933749],"genre_scores_gemma":[0.987971,0.0006909877,0.002643274,0.00007102988,0.000007868722,0.00005552208,0.001671701,0.00005199978,0.006836566],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01240579,"threshold_uncertainty_score":0.02466714,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009948845428946284,"score_gpt":0.2016034118215506,"score_spread":0.1916545663926043,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}