{"id":"W1979333464","doi":"10.1139/cjc-79-5-6-896","title":"Dithiophosphinates of gold (I); oxidative addition of Cl&lt;sub&gt;2&lt;/sub&gt; to a neutral, dinuclear gold(I) dithiophosphinate complex, and X-ray crystal structures of [AuS&lt;sub&gt;2&lt;/sub&gt;P(C&lt;sub&gt;2&lt;/sub&gt;H&lt;sub&gt;5&lt;/sub&gt;)&lt;sub&gt;2&lt;/sub&gt;]&lt;sub&gt;2&lt;/sub&gt;, [AuS&lt;sub&gt;2&lt;/sub&gt;PPh&lt;sub&gt;2&lt;/sub&gt;]&lt;sub&gt;2&lt;/sub&gt;, Au&lt;sub&gt;2&lt;/sub&gt;(CH&lt;sub&gt;2&lt;/sub&gt;)&lt;sub&gt;2&lt;/sub&gt;PMe&lt;sub&gt;2&lt;/sub&gt;(S&lt;sub&gt;2&lt;/sub&gt;PPh&lt;sub&gt;2&lt;/sub&gt;), and Au&lt;sub&gt;2&lt;/sub&gt;Cl&lt;sub&gt;2&lt;/sub&gt;[(CH&lt;sub&gt;2&lt;/sub&gt;)&lt;sub&gt;2&lt;/sub&gt;PMe&lt;sub&gt;2&lt;/sub&gt;][S&lt;sub&gt;2&lt;/sub&gt;PPh&lt;sub&gt;2&lt;/sub&gt;]","year":2001,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Organometallic Compounds Synthesis and Characterization","field":"Chemistry","cited_by":11,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Chemistry; Crystallography; Moiety; Oxidative addition; Ligand (biochemistry); Ylide; Crystal structure; Intermolecular force; Stereochemistry; Oxidation state; Molecule; Metal; Organic chemistry; Catalysis","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaresearch","metaepi_narrow","metaepi_broad","bibliometrics","sts","scholarly_communication","open_science","research_integrity","insufficient_payload"],"consensus_categories":["metaresearch","metaepi_narrow","metaepi_broad","bibliometrics","sts","scholarly_communication","open_science","research_integrity","insufficient_payload"],"category_scores_codex":[0.06912704,0.1072565,0.1007977,0.06303775,0.04705434,0.04379997,0.09579543,0.07178395,0.01708349],"category_scores_gemma":[0.03992057,0.1223259,0.06304912,0.08832417,0.06040763,0.05765549,0.05438791,0.0752494,0.02732158],"about_ca_system_candidate":true,"about_ca_system_consensus":true,"about_ca_system_score_codex":0.07462132,"about_ca_system_score_gemma":0.06064657,"about_ca_topic_candidate":true,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.003209911,"about_ca_topic_score_gemma":0.05838102,"domain_scores_codex":[0.6723469,0.03139717,0.08230873,0.07063919,0.06542566,0.07788237],"domain_scores_gemma":[0.7211593,0.0296269,0.07755446,0.06260032,0.04651953,0.06253944],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.03571358,0.03210735,0.003315971,0.02100241,0.03554456,0.02368052,0.01275849,0.009279946,0.5930091,0.0100662,0.1920706,0.0314513],"study_design_scores_gemma":[0.07338361,0.01612527,0.01375886,0.02765386,0.03583977,0.02069335,0.004527287,0.01265664,0.4493809,0.007097109,0.2579992,0.08088418],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.6648558,0.095706,0.004316736,0.01110175,0.04486946,0.05679308,0.07477786,0.02515388,0.02242541],"genre_scores_gemma":[0.6891695,0.1248028,0.006982048,0.01068863,0.04307966,0.02462236,0.0539424,0.03640372,0.01030886],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1436282,"threshold_uncertainty_score":0.983815,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009948845428946284,"score_gpt":0.2016034118215506,"score_spread":0.1916545663926043,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}