{"id":"W1979704658","doi":"10.1002/cctc.201000102","title":"Rhodium‐ and Iridium‐Catalyzed Hydroamination of Alkenes","year":2010,"lang":"en","type":"article","venue":"ChemCatChem","topic":"Catalytic C–H Functionalization Methods","field":"Chemistry","cited_by":222,"is_retracted":false,"has_abstract":true,"ca_institutions":"Dalhousie University","funders":"","keywords":"Hydroamination; Chemistry; Alkene; Catalysis; Intramolecular force; Combinatorial chemistry; Rhodium; Regioselectivity; Amination; Olefin fiber; Organic chemistry; Enantioselective synthesis; Context (archaeology)","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002279657,0.0003225509,0.0001386085,0.000177196,0.0001152403,0.0001799926,0.0003312022,0.0002326201,0.001514957],"category_scores_gemma":[0.000209999,0.0001360077,0.0002033025,0.00008124987,0.0001980863,0.0004001348,0.0002796561,0.0003878579,0.0006655034],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001942674,"about_ca_system_score_gemma":0.0001958625,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003434444,"about_ca_topic_score_gemma":0.0008885399,"domain_scores_codex":[0.9998449,0.00002442167,0.0000102079,0.00003252528,0.00004311596,0.0000447666],"domain_scores_gemma":[0.999915,0.00001688663,0.00002141652,0.0000170476,0.00001557455,0.00001395925],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000091791,0.00003132296,0.00009776573,0.0001412279,0.000009558614,0.0001865242,0.0000438208,0.0002998876,0.9900624,0.001112214,0.0001763907,0.007746988],"study_design_scores_gemma":[0.00001307164,0.0001087496,0.0003044993,0.000006042486,0.000006820028,0.0001570578,0.00001392327,0.0006340128,0.9952412,0.0001025711,0.003405943,0.000006236281],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9490908,0.005719888,0.01179312,0.000249812,0.0001126112,0.00008611342,0.0002466477,0.0001446103,0.03255651],"genre_scores_gemma":[0.9890895,0.00159344,0.003391767,0.00003937832,0.00001208828,0.00001616761,0.000132811,0.00001946626,0.005705403],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001514957,"threshold_uncertainty_score":0.005068064,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01373853069318613,"score_gpt":0.2688115685458061,"score_spread":0.2550730378526199,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}